DC Field | Value | Language |
---|---|---|
dc.contributor.author | Park, Myung-Hwan | ko |
dc.contributor.author | Yun, Chang-Hun | ko |
dc.contributor.author | Huh, Jung-Oh | ko |
dc.contributor.author | Do, Young-Kyu | ko |
dc.contributor.author | Yoo, Seung-Hyup | ko |
dc.contributor.author | Lee, Min-Hyung | ko |
dc.date.accessioned | 2013-03-11T02:38:11Z | - |
dc.date.available | 2013-03-11T02:38:11Z | - |
dc.date.created | 2012-02-06 | - |
dc.date.created | 2012-02-06 | - |
dc.date.issued | 2010-09 | - |
dc.identifier.citation | SYNTHETIC METALS, v.160, pp.2000 - 2007 | - |
dc.identifier.issn | 0379-6779 | - |
dc.identifier.uri | http://hdl.handle.net/10203/98055 | - |
dc.description.abstract | Palladium(II)-catalyzed polymerization of norbornene monomers bearing triarylamine side groups was investigated to prepare the vinyl-type polynorbornenes having hole-transporting properties. Norbornene monomers (M1-M3) with the ethyl ester linked aryldiphenylamines where the aryl group is phenyl, m-tolyl, and 1-naphthyl, respectively, were employed. The combined use of the Pd(II) catalyst supported by N-heterocyclic carbene ligand and AgSbF(6) leads to the production of soluble polynorbornenes (P1-P3). While the cyclic voltammetry measurements show the relatively low oxidational stability of polymers, the polymers exhibit the high glass transition temperature of 305-333 degrees C. The atomic force microscopy images of the thin film of P1 reveal the very smooth film surface with a roughness of 0.29 nm, indicating the good film-forming capability of polymer. When incorporated as a hole-transporting layer in Alq(3)-based electroluminescent devices, the spin-coated polymer films display hole-transporting property suitable for the proper green emission of Alq(3). Among the devices studied, the one based on 1-naphthylamine-containing P3 exhibits the highest performance in terms of luminance and external quantum efficiency. (C) 2010 Elsevier B.V. All rights reserved. | - |
dc.language | English | - |
dc.publisher | ELSEVIER SCIENCE SA | - |
dc.subject | LIGHT-EMITTING-DIODES | - |
dc.subject | ORGANIC ELECTROLUMINESCENT DEVICES | - |
dc.subject | ANODIC OXIDATION PATHWAYS | - |
dc.subject | N-HETEROCYCLIC CARBENE | - |
dc.subject | AROMATIC POLYAMIDES | - |
dc.subject | FUNCTIONALIZED NORBORNENES | - |
dc.subject | ADDITION POLYMERIZATION | - |
dc.subject | TRIPHENYLAMINE UNITS | - |
dc.subject | CONDUCTING POLYMERS | - |
dc.subject | POLYFLUORENE | - |
dc.title | Synthesis and hole-transporting properties of vinyl-type polynorbornenes with ethyl ester linked triarylamine side groups | - |
dc.type | Article | - |
dc.identifier.wosid | 000282462500030 | - |
dc.identifier.scopusid | 2-s2.0-77957926932 | - |
dc.type.rims | ART | - |
dc.citation.volume | 160 | - |
dc.citation.beginningpage | 2000 | - |
dc.citation.endingpage | 2007 | - |
dc.citation.publicationname | SYNTHETIC METALS | - |
dc.identifier.doi | 10.1016/j.synthmet.2010.07.025 | - |
dc.embargo.liftdate | 9999-12-31 | - |
dc.embargo.terms | 9999-12-31 | - |
dc.contributor.localauthor | Do, Young-Kyu | - |
dc.contributor.localauthor | Yoo, Seung-Hyup | - |
dc.contributor.nonIdAuthor | Lee, Min-Hyung | - |
dc.type.journalArticle | Article | - |
dc.subject.keywordAuthor | Addition polymerization | - |
dc.subject.keywordAuthor | Polynorbornene | - |
dc.subject.keywordAuthor | Triarylamine | - |
dc.subject.keywordAuthor | Hole-transporting materials | - |
dc.subject.keywordPlus | LIGHT-EMITTING-DIODES | - |
dc.subject.keywordPlus | ORGANIC ELECTROLUMINESCENT DEVICES | - |
dc.subject.keywordPlus | ANODIC OXIDATION PATHWAYS | - |
dc.subject.keywordPlus | N-HETEROCYCLIC CARBENE | - |
dc.subject.keywordPlus | AROMATIC POLYAMIDES | - |
dc.subject.keywordPlus | FUNCTIONALIZED NORBORNENES | - |
dc.subject.keywordPlus | ADDITION POLYMERIZATION | - |
dc.subject.keywordPlus | TRIPHENYLAMINE UNITS | - |
dc.subject.keywordPlus | CONDUCTING POLYMERS | - |
dc.subject.keywordPlus | POLYFLUORENE | - |
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