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College of Natural Sciences(자연과학대학)Dept. of Chemistry(화학과)CH-Journal Papers(저널논문)

A Nonclassical Dihydrogen Adduct of S=1/2 Fe(I)

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dc.contributor.authorLee, Yunhoko
dc.contributor.authorKinney, RAko
dc.contributor.authorHoffman, BMko
dc.contributor.authorPeters, JCko
dc.date.accessioned2013-03-09T09:30:29Z-
dc.date.available2013-03-09T09:30:29Z-
dc.date.created2012-02-06-
dc.date.created2012-02-06-
dc.date.issued2011-10-
dc.identifier.citationJOURNAL OF THE AMERICAN CHEMICAL SOCIETY, v.133, no.41, pp.16366 - 16369-
dc.identifier.issn0002-7863-
dc.identifier.urihttp://hdl.handle.net/10203/95992-
dc.description.abstractWe have exploited the capacity of the "(SiP3iPr)Fe(I)" scaffold to accommodate additional axial ligands and characterized the mononuclear S = 1/2 H-2 adduct complex (SiP3iPr)Fe-I(H-2). EPR and ENDOR data, in the context of X-ray structural results, revealed that this complex provides a highly unusual example of an open-shell metal complex that binds dihydrogen as a ligand. The H2 ligand at 2 K dynamically reorients within the ligand-binding pocket, tunneling among the energy minima created by strong interactions with the three Fe-P bonds.-
dc.languageEnglish-
dc.publisherAMER CHEMICAL SOC-
dc.subjectTRIS(PHOSPHINO)SILYL LIGANDS-
dc.subjectDINITROGEN COMPLEXES-
dc.subjectIRON-
dc.subjectEPR-
dc.subjectNITROGENASE-
dc.subjectROTATION-
dc.subjectENDOR-
dc.subjectNH3-
dc.subjectN-2-
dc.subjectH-2-
dc.titleA Nonclassical Dihydrogen Adduct of S=1/2 Fe(I)-
dc.typeArticle-
dc.identifier.wosid000295997500013-
dc.identifier.scopusid2-s2.0-80054730876-
dc.type.rimsART-
dc.citation.volume133-
dc.citation.issue41-
dc.citation.beginningpage16366-
dc.citation.endingpage16369-
dc.citation.publicationnameJOURNAL OF THE AMERICAN CHEMICAL SOCIETY-
dc.identifier.doi10.1021/ja207003m-
dc.contributor.localauthorLee, Yunho-
dc.contributor.nonIdAuthorKinney, RA-
dc.contributor.nonIdAuthorHoffman, BM-
dc.contributor.nonIdAuthorPeters, JC-
dc.type.journalArticleArticle-
dc.subject.keywordPlusTRIS(PHOSPHINO)SILYL LIGANDS-
dc.subject.keywordPlusDINITROGEN COMPLEXES-
dc.subject.keywordPlusIRON-
dc.subject.keywordPlusEPR-
dc.subject.keywordPlusNITROGENASE-
dc.subject.keywordPlusROTATION-
dc.subject.keywordPlusENDOR-
dc.subject.keywordPlusNH3-
dc.subject.keywordPlusN-2-
dc.subject.keywordPlusH-2-
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