DC Field | Value | Language |
---|---|---|
dc.contributor.author | Kwon, O-Pil | ko |
dc.contributor.author | Jazbinsek, Mojca | ko |
dc.contributor.author | Yun, Hoseop | ko |
dc.contributor.author | Seo, Jung-In | ko |
dc.contributor.author | Kim, Eun-Mi | ko |
dc.contributor.author | Lee, Yoon Sup | ko |
dc.contributor.author | Guenter, Peter | ko |
dc.date.accessioned | 2013-03-07T17:44:46Z | - |
dc.date.available | 2013-03-07T17:44:46Z | - |
dc.date.created | 2012-02-06 | - |
dc.date.created | 2012-02-06 | - |
dc.date.issued | 2008-11 | - |
dc.identifier.citation | CRYSTAL GROWTH & DESIGN, v.8, no.11, pp.4021 - 4025 | - |
dc.identifier.issn | 1528-7483 | - |
dc.identifier.uri | http://hdl.handle.net/10203/90813 | - |
dc.description.abstract | A series of new organic nonlinear optical nitrophenylhydrazone crystals based on pyrrole with various substituents (X: -H, -CH(3), -CF(3)) on the hydrazone group (-CX = N-NH-) has been synthesized and their polymorphs have been investigated. The chromophore 2-((2-(4-nitrophenyl)hydrazono)methyl)-1H-pyrrole (HNPH) exhibits two polymorphs with large macroscopic nonlinearity, with a powder second harmonic generation activity of 420 times and 210 times that of urea at 1.9 mu m for the anisotropic polar HNPH-I with P(n) space group and the isotropic nonpolar HNPH-II polymorph with P2(1)2(1)2(1) space group, respectively. The microscopic and macroscopic nonlinearities in the crystallographic system have been analyzed theoretically using finite field calculations. | - |
dc.language | English | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.subject | 1ST HYPERPOLARIZABILITY | - |
dc.subject | WAVE-GUIDES | - |
dc.subject | INFRARED-ABSORPTION | - |
dc.subject | MOLECULAR-CRYSTALS | - |
dc.subject | CHROMOPHORES | - |
dc.subject | GENERATION | - |
dc.subject | POLYENE | - |
dc.subject | DESIGN | - |
dc.subject | DONOR | - |
dc.subject | SALTS | - |
dc.title | Pyrrole-Based Hydrazone Organic Nonlinear Optical Crystals and Their Polymorphs | - |
dc.type | Article | - |
dc.identifier.wosid | 000260675500028 | - |
dc.identifier.scopusid | 2-s2.0-61549093395 | - |
dc.type.rims | ART | - |
dc.citation.volume | 8 | - |
dc.citation.issue | 11 | - |
dc.citation.beginningpage | 4021 | - |
dc.citation.endingpage | 4025 | - |
dc.citation.publicationname | CRYSTAL GROWTH & DESIGN | - |
dc.identifier.doi | 10.1021/cg800218u | - |
dc.contributor.localauthor | Lee, Yoon Sup | - |
dc.contributor.nonIdAuthor | Kwon, O-Pil | - |
dc.contributor.nonIdAuthor | Jazbinsek, Mojca | - |
dc.contributor.nonIdAuthor | Yun, Hoseop | - |
dc.contributor.nonIdAuthor | Kim, Eun-Mi | - |
dc.contributor.nonIdAuthor | Guenter, Peter | - |
dc.type.journalArticle | Article | - |
dc.subject.keywordPlus | 1ST HYPERPOLARIZABILITY | - |
dc.subject.keywordPlus | WAVE-GUIDES | - |
dc.subject.keywordPlus | INFRARED-ABSORPTION | - |
dc.subject.keywordPlus | MOLECULAR-CRYSTALS | - |
dc.subject.keywordPlus | CHROMOPHORES | - |
dc.subject.keywordPlus | GENERATION | - |
dc.subject.keywordPlus | POLYENE | - |
dc.subject.keywordPlus | DESIGN | - |
dc.subject.keywordPlus | DONOR | - |
dc.subject.keywordPlus | SALTS | - |
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.