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College of Natural Sciences(자연과학대학)Dept. of Chemistry(화학과)CH-Journal Papers(저널논문)

Gold(III)-catalyzed cyanosilylation of ketones and aldehydes

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dc.contributor.authorCho, WKko
dc.contributor.authorKang, SMko
dc.contributor.authorMedda, AKko
dc.contributor.authorLee, JKko
dc.contributor.authorChoi, Insungko
dc.contributor.authorLee, Hee-Seungko
dc.date.accessioned2013-03-07T06:05:01Z-
dc.date.available2013-03-07T06:05:01Z-
dc.date.created2012-02-06-
dc.date.created2012-02-06-
dc.date.issued2008-02-
dc.identifier.citationSYNTHESIS-STUTTGART, no.4, pp.507 - 510-
dc.identifier.issn0039-7881-
dc.identifier.urihttp://hdl.handle.net/10203/89556-
dc.description.abstractGold(III) chloride was found to be a highly efficient catalyst for the cyanosilylation of various ketones and aldehydes. The reactions were complete within 30 minutes at room temperature in the presence of only one mol% gold(III) chloride, yielding the corresponding cyanohydrin trimethylsilyl ethers in very good yields. The isolated yields for the reactions of ketones were up to 98%, and the reactions of aldehydes gave 100% conversion, as monitored by (1)H NMR spectroscopy.-
dc.languageEnglish-
dc.publisherGEORG THIEME VERLAG KG-
dc.subjectCATALYTIC ASYMMETRIC CYANOSILYLATION-
dc.subjectN-HETEROCYCLIC CARBENES-
dc.subjectTRIMETHYLSILYL CYANIDE-
dc.subjectCARBONYL-COMPOUNDS-
dc.subjectHIGHLY EFFICIENT-
dc.subjectENANTIOSELECTIVE TRIMETHYLSILYLCYANATION-
dc.subjectSYNTHETIC APPLICATIONS-
dc.subjectHOMOGENEOUS CATALYSIS-
dc.subjectGOLD-
dc.subjectALKYNES-
dc.titleGold(III)-catalyzed cyanosilylation of ketones and aldehydes-
dc.typeArticle-
dc.identifier.wosid000253635600002-
dc.type.rimsART-
dc.citation.issue4-
dc.citation.beginningpage507-
dc.citation.endingpage510-
dc.citation.publicationnameSYNTHESIS-STUTTGART-
dc.identifier.doi10.1055/s-2008-1032154-
dc.contributor.localauthorChoi, Insung-
dc.contributor.localauthorLee, Hee-Seung-
dc.contributor.nonIdAuthorCho, WK-
dc.contributor.nonIdAuthorKang, SM-
dc.contributor.nonIdAuthorMedda, AK-
dc.contributor.nonIdAuthorLee, JK-
dc.type.journalArticleArticle-
dc.subject.keywordAuthorcyanohydrins-
dc.subject.keywordAuthortransition metals-
dc.subject.keywordAuthorhomogeneous catalysis-
dc.subject.keywordAuthorketones-
dc.subject.keywordAuthoraldehydes-
dc.subject.keywordPlusCATALYTIC ASYMMETRIC CYANOSILYLATION-
dc.subject.keywordPlusN-HETEROCYCLIC CARBENES-
dc.subject.keywordPlusTRIMETHYLSILYL CYANIDE-
dc.subject.keywordPlusCARBONYL-COMPOUNDS-
dc.subject.keywordPlusHIGHLY EFFICIENT-
dc.subject.keywordPlusENANTIOSELECTIVE TRIMETHYLSILYLCYANATION-
dc.subject.keywordPlusSYNTHETIC APPLICATIONS-
dc.subject.keywordPlusHOMOGENEOUS CATALYSIS-
dc.subject.keywordPlusGOLD-
dc.subject.keywordPlusALKYNES-
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