Phosphoryl azides as versatile new reaction partners in the Cu-catalyzed three-component couplings

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[GRAPHICS] Phosphoryl azide was successfully employed as an efficient reacting partner in the Cu-catalyzed three-component reaction with 1-alkynes and amines to produce the corresponding phosphoryl amidines in high yields. A range of fruitful applicability of the produced amidines was also demonstrated such as an alkoxide exchange and asymmetric alpha-alkylation of optically active BINOL-derived amidines.
Publisher
AMER CHEMICAL SOC
Issue Date
2007-12
Language
English
Article Type
Article
Keywords

ONE-POT SYNTHESIS; TERMINAL ALKYNES; SULFONYL AZIDE; AMIDE SYNTHESIS; AMIDINES; AZIRIDINATION; ALKENES; WATER; ACIDS

Citation

JOURNAL OF ORGANIC CHEMISTRY, v.72, no.25, pp.9769 - 9771

ISSN
0022-3263
URI
http://hdl.handle.net/10203/89149
Appears in Collection
CH-Journal Papers(저널논문)
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