The effects of electroplating parameters on the composition and morphology of Sn-Ag solder

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The Sn-Ag solder was electrodeposited from a bath that basically is composed of tin sulfate (SnSO4), silver nitrate (AgNO3), and thiourea (CH4N2S), acting as a complexing agent to silver. The composition and morphology of electrodeposited Sn-Ag solder were studied in terms of silver concentration in bath current density, duty cycle, and additives. It was possible to control silver content in the electrodeposit by means of varying silver concentration in bath and current density. The microstructure and surface morphology of the electrodeposit become finer and smoother with increasing current density. The pulse-current (PC) plating method was applied to compare to the conventional direct-current (DC) plating. Varying duty cycle in PC plating did not change the microstructure in general, but some improvement in surface roughness was observed compared to DC plating. However, the silver composition in the electrodeposit increased with decreasing the duty cycle at a constant current density. An addition of a surface-active agent helped to reduce the surface roughness and the variation of silver content in the electrodeposit. In an optimum condition, eutectic Sn-Ag solder bumps with a fine pitch of 30 mum and height of 15 mum were successfully electroplated. The composition of Sn-Ag bumps was analyzed by energy dispersive x-ray spectrometry (EDS) and wavelength dispersive x-ray spectrometry (WDS) methods, and the surface morphology was characterized by scanning electron microscopy (SEM) and a three-dimensional surface analyzer.
Publisher
SPRINGER
Issue Date
2004-12
Language
English
Article Type
Article; Proceedings Paper
Citation

JOURNAL OF ELECTRONIC MATERIALS, v.33, no.12, pp.1459 - 1464

ISSN
0361-5235
URI
http://hdl.handle.net/10203/82730
Appears in Collection
MS-Journal Papers(저널논문)
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