Application of sulfur ylide mediated epoxidations in the asymmetric synthesis of beta-hydroxy-delta-lactones. Synthesis of a mevinic acid analogue and (+)-prelactone B

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Catalytic and stoichiometric asymmetric sulfur ylide reactions were employed to prepare alkyl-aryl epoxide intermediates in a convergent manner. These epoxides were utilized in efficient syntheses of the mevinic acid analogue 1 and prelactone B. (C) 2004 Elsevier Ltd. All rights reserved.
Publisher
PERGAMON-ELSEVIER SCIENCE LTD
Issue Date
2004-10
Language
English
Article Type
Article
Keywords

IN-SITU GENERATION; PRELACTONE-B; ENANTIOSELECTIVE SYNTHESIS; 3-HYDROXY-3-METHYLGLUTARYL-COENZYME-A REDUCTASE; PHOSPHAZENE BASE; DIAZO-COMPOUNDS; EPOXIDES; (+)-COMPACTIN; INHIBITORS; MEVINOLIN

Citation

TETRAHEDRON, v.60, no.43, pp.9725 - 9733

ISSN
0040-4020
URI
http://hdl.handle.net/10203/82511
Appears in Collection
CH-Journal Papers(저널논문)
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