DC Field | Value | Language |
---|---|---|
dc.contributor.author | Joo, SW | ko |
dc.contributor.author | Han, Sang Woo | ko |
dc.contributor.author | Kim, K | ko |
dc.date.accessioned | 2013-03-02T20:48:03Z | - |
dc.date.available | 2013-03-02T20:48:03Z | - |
dc.date.created | 2012-02-06 | - |
dc.date.created | 2012-02-06 | - |
dc.date.created | 2012-02-06 | - |
dc.date.issued | 2000-07 | - |
dc.identifier.citation | JOURNAL OF PHYSICAL CHEMISTRY B, v.104, no.26, pp.6218 - 6224 | - |
dc.identifier.issn | 1089-5647 | - |
dc.identifier.uri | http://hdl.handle.net/10203/75457 | - |
dc.description.abstract | The adsorption behavior of 1,3-propanedithiol (1,3-PDT) on a colloidal gold surface has been investigated by means of surface-enhanced Raman scattering (SERS). 1,3-PDT chemisorbed dissociatively on gold as a monothiolate. Moreover, we could clearly identify the S-S stretching band that reveals the formation of multilayers of 1,3-PDT on the colloidal gold surface. As for the case of 1,2-ethanedithiol. the intermolecular disulfide bond appeared to form even at a submonolayer coverage limit, implying that the adsorption of alpha,omega-alkanedithiol on gold does not take place homogeneously from the early stages of self-assembly. On the other hand, referring to the ab initio calculated vibrational frequencies of AuSCH2CH2CH2Cl, we could also analyze the concentration-dependent SER spectral features of 1,3-PDT in terms of the conformational isomerism around the two C-S bonds. Upon the increase of the bulk concentration of 1,3-PDT, a transition from a GG to GT conformation appeared to occur on the sol surface near the monolayer coverage limit; herein the first letter designates the conformation with respect to the C-C bond near the gold surface. On the basis of the concentration-dependent SER peak intensities, the 1,3-PDT-derivatized Au particles appeared to consist in nearly contact configurations. A separate ellipsometry measurement performed with vacuum-evaporated gold substrate revealed that at best one and one-half layered film could be assembled on gold in polar and protic solvents while up to three layers were assembled on gold in n-hexane solution of 1,3-PDT. | - |
dc.language | English | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.title | Adsorption characteristics of 1,3-propanedithiol on gold: Surface-enhanced Raman scattering and ellipsometry study | - |
dc.type | Article | - |
dc.identifier.wosid | 000088057100020 | - |
dc.identifier.scopusid | 2-s2.0-0034227919 | - |
dc.type.rims | ART | - |
dc.citation.volume | 104 | - |
dc.citation.issue | 26 | - |
dc.citation.beginningpage | 6218 | - |
dc.citation.endingpage | 6224 | - |
dc.citation.publicationname | JOURNAL OF PHYSICAL CHEMISTRY B | - |
dc.identifier.doi | 10.1021/jp0001790 | - |
dc.contributor.localauthor | Han, Sang Woo | - |
dc.contributor.nonIdAuthor | Joo, SW | - |
dc.contributor.nonIdAuthor | Kim, K | - |
dc.type.journalArticle | Article | - |
dc.subject.keywordPlus | SELF-ASSEMBLED MONOLAYERS | - |
dc.subject.keywordPlus | ATOMIC-FORCE MICROSCOPY | - |
dc.subject.keywordPlus | TRANSFORM INFRARED-SPECTROSCOPY | - |
dc.subject.keywordPlus | QUARTZ-CRYSTAL MICROBALANCE | - |
dc.subject.keywordPlus | X-RAY | - |
dc.subject.keywordPlus | STRUCTURAL CHARACTERIZATION | - |
dc.subject.keywordPlus | SILVER SURFACE | - |
dc.subject.keywordPlus | AU(111) | - |
dc.subject.keywordPlus | 1,8-OCTANEDITHIOL | - |
dc.subject.keywordPlus | FILM | - |
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