Low-temperature crystallization of amorphous silicon (a-Si) films by adsorbing metal on the films was investigated. Amorphous Si films were deposited by low-pressure chemical vapor deposition, spin-coated by metal solutions and subsequently annealed in Ar atmosphere. Polycrystalline silicon (poly-Si) thin-film transistors (TFT) were fabricated using the annealed Si films with Cu adsorption. And the thermodynamic parameters were extracted by observing crystallization behaviors.