A Lewis acid dependent asymmetric Diels-Alder process in the cyclization of new chiral acrylamides with dienes

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Diels-Alder cycloadditions of chiral acrylamides with cyclopentadiene proceed with high diastereofacial selectivity, giving either endo-R to endo-S products depending of the Lewis acid used.
Publisher
ROYAL SOC CHEMISTRY
Issue Date
1999-06
Language
English
Article Type
Article
Keywords

(S)-PROLINE BENZYL ESTER; N-ACYLOXAZOLIDINONE; AUXILIARIES; DIENOPHILES; 2-OXAZOLONE; INDUCTION; ADDITIONS; CAMPHOR

Citation

CHEMICAL COMMUNICATIONS, pp.963 - 964

ISSN
1359-7345
URI
http://hdl.handle.net/10203/70581
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