Palladium catalyzed alkenylation or alkynylation at C-5 of uracil nucleosides using novel phenyliodonium triflate

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A new coupling reaction between novel uracil-5-iodonium triflate and unsaturated stannane or alkenyl boronic acid is described. The reaction is achieved via palladium catalyzed cross-coupling reaction under mild conditions within short reaction time. (C) 1999 Elsevier Science Ltd. All rights reserved.
Publisher
PERGAMON-ELSEVIER SCIENCE LTD
Issue Date
1999-03
Language
English
Article Type
Article
Keywords

CROSS-COUPLING REACTIONS; ACTIVATED VINYL HALIDES; STEREOSPECIFIC SYNTHESIS; PYRIMIDINE NUCLEOSIDES; ORGANOBORON COMPOUNDS; ANTIVIRAL ACTIVITY; IODONIUM SALTS; ORGANOSTANNANES

Citation

TETRAHEDRON LETTERS, v.40, no.10, pp.1903 - 1906

ISSN
0040-4039
DOI
10.1016/S0040-4039(98)02491-5
URI
http://hdl.handle.net/10203/69753
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