1,5-Hydrogen Transfers from Carbon to N-Tributyltin Substituted Nitrogen

Abstract

1,5-H transfers from carbon to N-tributyltin substituted nitrogen proceeded smoothly and were much more efficient than 1,5-H transfers from carbon to ordinary nitrogen. 1,5-Tribuyltin group transfer from carbon to nitrogen and intramolecular addition of an aminyl radical to a nirile group were also observed for the first time. (C) 1997 Elsevier Science Ltd.