(3)DELTA-(1)SIGMA+ TRANSITION OF RBCS OBSERVED IN A VERY COLD MOLECULAR-BEAM
A new excitation band of RbCs is observed near 605 nm in a very cold molecular beam using the resonance-enhanced two photon ionization (RE2PI) method. From the rotational contour analysis and comparison with ab initio calcualtions, the new excitation band is assigned to the (1)3DELTA(OMEGA = 1)-X 1SIGMA+ transition. We determine the term value as T(e) = 16481.65 +/- 0.15 cm-1 and the dissociation energy as D(e) = 1862.8 +/- 1.2 cm-1.
- Publisher
- ELSEVIER SCIENCE BV
- Issue Date
- 1993-09
- Language
- English
- Article Type
- Article
- Keywords
LASER-INDUCED FLUORESCENCE; 1-SIGMA+ GROUND-STATE; ROTATIONAL ANALYSIS; SPECTROSCOPIC INVESTIGATIONS; CS2
- Citation
CHEMICAL PHYSICS LETTERS, v.212, no.3-4, pp.271 - 276
- ISSN
- 0009-2614
- Appears in Collection
- CH-Journal Papers(저널논문)
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