Diffusion Coefficients for One Composition of the System Water-Tetrabutylammonium Bromide-Hydrogen Bromide at 25 degrees C

Cited 6 time in webofscience Cited 0 time in scopus
  • Hit : 349
  • Download : 0
Four diffusion coefficients for one composition of the system H(2)O-Bu(4)NBr-HBr were obtained at 25 degrees C. The value of (D(12))(v) was negative and large as expected from the primary charge effect. However, the value of (D(21))(v) was also negative despite the fact that the primary charge effect predicts a positive value. This was interpreted to be a consequence of a large negative value for In y(2)/partial derivative C(1) which overshadows the primary charge effect.
Publisher
Springer/Plenum Publishers
Issue Date
1974-06
Language
English
Article Type
Article
Citation

JOURNAL OF SOLUTION CHEMISTRY, v.3, no.6, pp.445 - 453

ISSN
0095-9782
DOI
10.1007/BF00651535
URI
http://hdl.handle.net/10203/62941
Appears in Collection
Files in This Item
There are no files associated with this item.
This item is cited by other documents in WoS
⊙ Detail Information in WoSⓡ Click to see webofscience_button
⊙ Cited 6 items in WoS Click to see citing articles in records_button

qr_code

  • mendeley

    citeulike


rss_1.0 rss_2.0 atom_1.0