Synthesis of α-chloroketones from secondary alcohols using dichloramine-T이차 알코올로부터 다이클로라민-티를 이용한 알파클로로케톤의 합성

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dc.contributor.advisorKim, Yong-Hae-
dc.contributor.advisor김용해-
dc.contributor.authorLee, In-Sang-
dc.contributor.author이인상-
dc.date.accessioned2011-12-13T04:58:33Z-
dc.date.available2011-12-13T04:58:33Z-
dc.date.issued1990-
dc.identifier.urihttp://library.kaist.ac.kr/search/detail/view.do?bibCtrlNo=67106&flag=dissertation-
dc.identifier.urihttp://hdl.handle.net/10203/32577-
dc.description학위논문(석사) - 한국과학기술원 : 화학과, 1990.2, [ v, 47 p. ]-
dc.description.abstractVarious secondary alcohols reacted with dichloramine-T in $CH_3CN$ at $40^{\circ}C$ to give the corresponding α-chloroketones in good yields under mild and neutral conditions. This new method for the synthesis of α-chloroketones from secondary alcohol was accomplished by oxidation of secondary alcohols with dichloramine-T and then $\underline{in}$ $\underline{situ}$., followed by α-chlorination of the ketone. The reaction rate is strongly dependent on the nature of the substrate and substituent on the pheny ring moiety. Among the various solvents, acetonitrile showed by best results. The key to the success of this method appears to use aprotic polar solvent such as acetonitrile.eng
dc.languageeng-
dc.publisher한국과학기술원-
dc.titleSynthesis of α-chloroketones from secondary alcohols using dichloramine-T-
dc.title.alternative이차 알코올로부터 다이클로라민-티를 이용한 알파클로로케톤의 합성-
dc.typeThesis(Master)-
dc.identifier.CNRN67106/325007-
dc.description.department한국과학기술원 : 화학과, -
dc.identifier.uid000881362-
dc.contributor.localauthorKim, Yong-Hae-
dc.contributor.localauthor김용해-
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CH-Theses_Master(석사논문)
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