(A) convenient synthesis of Diethyl〔alkyl(or aryl) thio〕Vinyl Phosphonates = 디에틸 알킬티오 혹은 아릴티오 비닐포스폰네이트의 용이한 합성

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A convenient synthesis of $\alpha$-alkyl(or aryl) thio substituted vinyl phosphonates has been studied. Treatment or $\alpha$-sulfinyl phosphonates with trimethylsilyl triflate in the presence of hexamethyldisilazane and ethyl ether gives the corresponding vinyl phosphonates in good yields under the mild conditions. This reaction proceeds via Pummerer-type rearrangement of $\alpha$-sulfinyl phosphonates in the presence of weak base.
Advisors
Shim, Sang-Chul심상철
Description
한국과학기술원 : 화학과,
Publisher
한국과학기술원
Issue Date
1987
Identifier
65509/325007 / 000851002
Language
eng
Description

학위논문(석사) - 한국과학기술원 : 화학과, 1987.2, [ [iv], 72 p. ]

URI
http://hdl.handle.net/10203/32472
Link
http://library.kaist.ac.kr/search/detail/view.do?bibCtrlNo=65509&flag=dissertation
Appears in Collection
CH-Theses_Master(석사논문)
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