Graphene oxide-based nanofluidic system for power generation from salinity difference

Abstract

In converting a salinity difference to the electrical power by using an ion-selective membrane, achieving a high-power density necessitates both a high ion permeability and ion selectivity of the membrane. However, meeting these two requirements often leads to the conflicting tradeoff in the membrane properties. In this study, we introduce a new mechanistic approach to meeting both requirements by combining an ultra-thin (<100 nm thickness) graphene oxide-based membrane for a high permeability with an asymmetric access area for a high ion selectivity, forming a new type of ionic-diode nanofluidic system. With a graphene oxide/silk fibroin composite membrane, a large power density of 2kW/m(2) is achieved with 32% conversion efficiency under a 1000-fold salt concentration ratio. This approach can be utilized to overcome the low power density limitation with any ultra-thin membranes, and thereby it will provide a new route to utilize blue energy in a reliable and efficient way.