Uniform and scalable Sm3+ and Nd3+ doped ceria nanocatalysts decorating bifunctional oxygen electrodes for high performing reversible solid oxide electrochemical cells

Cited 3 time in webofscience Cited 0 time in scopus
  • Hit : 109
  • Download : 0
Surface modification with nanoparticles has been widely studied to promote catalytic activity and stability of the oxygen electrode in solid oxide electrochemical cells (SOCs). However, attaining uniformity and scalability of the nanoparticles remains a challenging endeavor. Herein, we developed a highly conductive nano-sized Sm3+ and Nd3+ double-doped ceria decorated La0.6Sr0.4Co0.2Fe0.8O3-δ -Gd0.1Ce0.9O2- δ (SNDC@LSCF-GDC) oxygen electrode via an ultrasonic spray infiltration technique. The uniform SNDC infiltrates promote oxygen catalytic activity by increasing oxygen vacancies and reaction sites on the surface of the electrode. The SOC with the SNDC@LSCF-GDC oxygen electrode shows high performance in fuel cell (1.97 W/cm2 at 750 °C) and electrolysis cell (1.72 A/cm2 at 750 °C) modes. Moreover, ultrasonic infiltration-based SNDC nanoparticles were successfully demonstrated in a large-size commercial cell (10 cm × 10 cm effective area), showing increased power output and remarkable stability for 960 h. This work presents a scalable and feasible way to decorate large area electrodes with uniform infiltrates for energy storage and conversion applications.
Publisher
ELSEVIER SCIENCE SA
Issue Date
2023-11
Language
English
Article Type
Article
Citation

CHEMICAL ENGINEERING JOURNAL, v.475

ISSN
1385-8947
DOI
10.1016/j.cej.2023.146002
URI
http://hdl.handle.net/10203/315207
Appears in Collection
ME-Journal Papers(저널논문)
Files in This Item
There are no files associated with this item.
This item is cited by other documents in WoS
⊙ Detail Information in WoSⓡ Click to see webofscience_button
⊙ Cited 3 items in WoS Click to see citing articles in records_button

qr_code

  • mendeley

    citeulike


rss_1.0 rss_2.0 atom_1.0