Oxidation using of peroxy intermediates and new chiral oxidizing reagents = 과산화 중간체들과 새로운 입체활성을 가지는 산화제들을 이용한 산화반응

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The Oxidation of various substrates such as benzylic methylenes, sulfides, thiophosphates, and nitroalkane was carried out by peroxy intermediates in situ generated from organo halides and superoxide. The chemical reactivities of these peroxy intermediates were studied by chemical experiments and the radical species of these intermediates were confirmed by spin trapping studies. In connection with the metabolic oxidation of nucleosides and insecticides, biominic oxidation of various substrates such as inosine, parathion, thiouridine, and aldrin by peroxy intermediates was examined. A new oxidizing agent of iodosobenzene and benzeneseleninic acid as a catalyst has been developed and used for the stepwise and chemoselective oxidation of sulfides. Asymmetric oxidation of sulfides and asymmetric $\alpha$ hydroxylation of carbonyl compounds were studied using new chiral oxidants.
Advisors
Kim, Yong-Hae김용해
Description
한국과학기술원 : 화학과,
Publisher
한국과학기술원
Issue Date
1990
Identifier
61430/325007 / 000865034
Language
eng
Description

학위논문(박사) - 한국과학기술원 : 화학과, 1990.8, [ xiii, 222 p. ]

URI
http://hdl.handle.net/10203/31335
Link
http://library.kaist.ac.kr/search/detail/view.do?bibCtrlNo=61430&flag=dissertation
Appears in Collection
CH-Theses_Ph.D.(박사논문)
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