Two-dimensional Zn(II) coordination polymer and hydrogen bond-mediated two-dimensional Cu(II) network based on trans-2-aminocyclopentanecarboxylate

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Coordination polymers from alpha-amino acids are promising organic-inorganic hybrid composites with chirality and biocompatibility. However, coordination polymers from unnatural amino acids are rarely studied. Here, we report the transition metal complexes from an unnatural beta-amino acid, (1S,2S)-2-aminocyclopentanecarboxylic acid, affording two possible coordination modes from the conformationally rigid cyclopentane ring. X-ray crystallographic analysis revealed that Zn(II) formed a two-dimensional (2D) coordination polymer via N,O-bridging mode. In contrast, Cu(II) formed a discrete complex via N,O-chelating mode and then constructed a 2D supramolecular network stabilized by hydrogen bonding between water and the ligands.
Publisher
WILEY-V C H VERLAG GMBH
Issue Date
2022-11
Language
English
Article Type
Article
Citation

BULLETIN OF THE KOREAN CHEMICAL SOCIETY, v.43, no.11, pp.1278 - 1283

ISSN
0253-2964
DOI
10.1002/bkcs.12615
URI
http://hdl.handle.net/10203/301387
Appears in Collection
CH-Journal Papers(저널논문)
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