DC Field | Value | Language |
---|---|---|
dc.contributor.author | Jones, Kerry E. | ko |
dc.contributor.author | Park, Bohyun | ko |
dc.contributor.author | Doering, Nicolle A. | ko |
dc.contributor.author | Baik, Mu-Hyun | ko |
dc.contributor.author | Sarpong, Richmond | ko |
dc.date.accessioned | 2022-02-22T06:44:02Z | - |
dc.date.available | 2022-02-22T06:44:02Z | - |
dc.date.created | 2022-02-22 | - |
dc.date.issued | 2021-12 | - |
dc.identifier.citation | JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, v.143, no.48, pp.20482 - 20490 | - |
dc.identifier.issn | 0002-7863 | - |
dc.identifier.uri | http://hdl.handle.net/10203/292355 | - |
dc.description.abstract | Reported here are substrate-dictated rearrangements of chrysanthenol derivatives prepared from verbenone to access complex bicyclic frameworks. These rearrangements set the stage for a 10-step formal synthesis of the natural product xishacorene B. Key steps include an anionic allenol oxy-Cope rearrangement and a Sua ' rez directed C-H functionalization. The success of this work was guided by extensive computational calculations which provided invaluable insight into the reactivity of the chrysanthenol-derived systems, especially in the key oxy-Cope rearrangement. | - |
dc.language | English | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.title | Rearrangements of the Chrysanthenol Core: Application to a Formal Synthesis of Xishacorene B | - |
dc.type | Article | - |
dc.identifier.wosid | 000750743100054 | - |
dc.identifier.scopusid | 2-s2.0-85120308543 | - |
dc.type.rims | ART | - |
dc.citation.volume | 143 | - |
dc.citation.issue | 48 | - |
dc.citation.beginningpage | 20482 | - |
dc.citation.endingpage | 20490 | - |
dc.citation.publicationname | JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | - |
dc.identifier.doi | 10.1021/jacs.1c10804 | - |
dc.contributor.localauthor | Baik, Mu-Hyun | - |
dc.contributor.nonIdAuthor | Jones, Kerry E. | - |
dc.contributor.nonIdAuthor | Doering, Nicolle A. | - |
dc.contributor.nonIdAuthor | Sarpong, Richmond | - |
dc.description.isOpenAccess | N | - |
dc.type.journalArticle | Article | - |
dc.subject.keywordPlus | KETONES | - |
dc.subject.keywordPlus | EFFICIENT | - |
dc.subject.keywordPlus | ALKOXY | - |
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