DC Field | Value | Language |
---|---|---|
dc.contributor.author | Kim, S.-J. | ko |
dc.contributor.author | Yu, I.C. | ko |
dc.contributor.author | Lee, J.-A. | ko |
dc.contributor.author | Kim, W.T. | ko |
dc.contributor.author | Jazbinsek, M. | ko |
dc.contributor.author | Yoon, W. | ko |
dc.contributor.author | Yun, H. | ko |
dc.contributor.author | Rotermund, Fabian | ko |
dc.contributor.author | Kwon, O.-P. | ko |
dc.date.accessioned | 2021-12-24T06:44:28Z | - |
dc.date.available | 2021-12-24T06:44:28Z | - |
dc.date.created | 2021-12-23 | - |
dc.date.created | 2021-12-23 | - |
dc.date.created | 2021-12-23 | - |
dc.date.issued | 2021-05 | - |
dc.identifier.citation | DYES AND PIGMENTS, v.192 | - |
dc.identifier.issn | 0143-7208 | - |
dc.identifier.uri | http://hdl.handle.net/10203/291128 | - |
dc.description.abstract | In this study, we develop new organic benzothiazolium crystals possessing very large off-diagonal optical nonlinearity. In these crystals, benzothiazolium-based 2-(4-(4-(hydroxymethyl)piperidin-1-yl)styryl)-3-methylbenzothiazol-3-ium (PMB) cations with large molecular optical nonlinearity are incorporated with two anions: 4-(trifluoromethoxy)benzenesulfonate (TFO) with an orthogonal non-planar shape and 5-bromothiophene-2-sulfonate (BTS) with a planar shape. Both PMB-TFO and PMB-BTS crystals exhibit state-of-the-art off-diagonal effective hyperpolarizability (~105 × 10−30 esu) that results from the V-shape and X-shape alignments of PMB chromophores, respectively. Newly developed PMB crystals indicate excellent characteristics for second-order nonlinear optical applications such as difference-frequency generation (e.g. optical rectification) and sum-frequency generation (e.g. second-harmonic generation), which are comparable to current benchmark organic crystals. © 2021 Elsevier Ltd | - |
dc.language | English | - |
dc.publisher | ELSEVIER SCI LTD | - |
dc.title | New benzothiazolium crystals with very large off-diagonal optical nonlinearity | - |
dc.type | Article | - |
dc.identifier.wosid | 000729946600002 | - |
dc.identifier.scopusid | 2-s2.0-85106384988 | - |
dc.type.rims | ART | - |
dc.citation.volume | 192 | - |
dc.citation.publicationname | DYES AND PIGMENTS | - |
dc.identifier.doi | 10.1016/j.dyepig.2021.109433 | - |
dc.contributor.localauthor | Rotermund, Fabian | - |
dc.contributor.nonIdAuthor | Kim, S.-J. | - |
dc.contributor.nonIdAuthor | Lee, J.-A. | - |
dc.contributor.nonIdAuthor | Jazbinsek, M. | - |
dc.contributor.nonIdAuthor | Yoon, W. | - |
dc.contributor.nonIdAuthor | Yun, H. | - |
dc.contributor.nonIdAuthor | Kwon, O.-P. | - |
dc.description.isOpenAccess | N | - |
dc.type.journalArticle | Article | - |
dc.subject.keywordAuthor | Chromophores | - |
dc.subject.keywordAuthor | Nonlinear optics | - |
dc.subject.keywordAuthor | Organic crystals | - |
dc.subject.keywordAuthor | THz wave generation | - |
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