Sodium fluoride-rich solid electrolyte interphase for sodium-metal and sodium-oxygen batteries

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We studied solid electrolyte interphase (SEI) on metallic sodium (Na) electrodes. Among sodium hexafluorophosphate (NaPF6), sodium triflate (NaOTf), and sodium bis(trifluoromethanesulfonyl)imide (NaTFSI) electrolytes, sodium fluoride (NaF)-rich and compact SEI was only formed by chemical reduction of NaPF6. Excellent rigidity and insolubility of NaF-rich SEI layer enhanced electrochemical cycling performances for both Na/Na symmetric cells and sodium-oxygen (Na-O-2) cells. By contrast, the Na electrodes using NaOTf and NaTFSI formed porous and carbonaceous SEI layers rather than NaF. Soluble carbonaceous species were detached from the Na electrode, which led to the undesired decomposition of electrolyte solution. It resulted in the substantial formation of the dead Na and dendritic Na and caused cycling failure of Na-O-2 cells within 10 cycles, demonstrated by NaOTf.
Publisher
WILEY-V C H VERLAG GMBH
Issue Date
2021-11
Language
English
Article Type
Article
Citation

BULLETIN OF THE KOREAN CHEMICAL SOCIETY, v.42, no.11, pp.1519 - 1523

ISSN
0253-2964
DOI
10.1002/bkcs.12381
URI
http://hdl.handle.net/10203/289587
Appears in Collection
CH-Journal Papers(저널논문)
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