DC Field | Value | Language |
---|---|---|
dc.contributor.author | Lee, Dong Woo | ko |
dc.contributor.author | Kim, Tae-Hyeong | ko |
dc.contributor.author | Lee, Jeongmook | ko |
dc.contributor.author | Park, Junghwan | ko |
dc.contributor.author | Kim, Jong-Yun | ko |
dc.contributor.author | Ok, Kang Min | ko |
dc.contributor.author | Lim, Sang Ho | ko |
dc.date.accessioned | 2021-11-23T06:43:32Z | - |
dc.date.available | 2021-11-23T06:43:32Z | - |
dc.date.created | 2021-11-22 | - |
dc.date.created | 2021-11-22 | - |
dc.date.created | 2021-11-22 | - |
dc.date.issued | 2021-10 | - |
dc.identifier.citation | INORGANIC CHEMISTRY, v.60, no.20, pp.15091 - 15095 | - |
dc.identifier.issn | 0020-1669 | - |
dc.identifier.uri | http://hdl.handle.net/10203/289378 | - |
dc.description.abstract | We provide the material synthesis method, crystal structure information, and characterization of a novel mixed-valent metal oxide (KIn0.33Te0.67Te2O7)-Te-III-Te-VI-O-IV, closely related to zirconolite (CaZrTi2O7), a radioactive waste immobilized material, having a 3D framework. The reported metal oxide containing an alkali-metal cation (K+), main-group cation (In3+), tellurate, and tellurite has been synthesized as both single crystals and a pure polycrystalline phase through a hydrothermal synthesis method. Single-crystal X-ray diffraction indicates that KIn0.33Te2.67O7 crystallizing in the orthorhombic space group Cmcm (No. 63) reveals a 3D framework structure with a 1D channel consisting of Te/InO6 octahedra and TeO4 polyhedra. An interesting transition reaction from KIn0.33Te2.67O7 to KIn(TeO3)(2) under hydrothermal conditions at 230 degrees C is discussed. | - |
dc.language | English | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.title | (KIn0.33Te0.67Te2O7)-Te-III-Te-VI-O-IV: Zirconolite-like Mixed-Valent Metal Oxide with a 3D Framework | - |
dc.type | Article | - |
dc.identifier.wosid | 000710270100006 | - |
dc.identifier.scopusid | 2-s2.0-85117110244 | - |
dc.type.rims | ART | - |
dc.citation.volume | 60 | - |
dc.citation.issue | 20 | - |
dc.citation.beginningpage | 15091 | - |
dc.citation.endingpage | 15095 | - |
dc.citation.publicationname | INORGANIC CHEMISTRY | - |
dc.identifier.doi | 10.1021/acs.inorgchem.1c01996 | - |
dc.embargo.liftdate | 9999-12-31 | - |
dc.embargo.terms | 9999-12-31 | - |
dc.contributor.localauthor | Park, Junghwan | - |
dc.contributor.nonIdAuthor | Lee, Dong Woo | - |
dc.contributor.nonIdAuthor | Kim, Tae-Hyeong | - |
dc.contributor.nonIdAuthor | Lee, Jeongmook | - |
dc.contributor.nonIdAuthor | Kim, Jong-Yun | - |
dc.contributor.nonIdAuthor | Ok, Kang Min | - |
dc.contributor.nonIdAuthor | Lim, Sang Ho | - |
dc.description.isOpenAccess | N | - |
dc.type.journalArticle | Article | - |
dc.subject.keywordPlus | 2ND-HARMONIC GENERATING PROPERTIES | - |
dc.subject.keywordPlus | LONE-PAIR CATION | - |
dc.subject.keywordPlus | TE-IV-O | - |
dc.subject.keywordPlus | NONCENTROSYMMETRIC TELLURITE | - |
dc.subject.keywordPlus | QUATERNARY TELLURITES | - |
dc.subject.keywordPlus | CRYSTAL-STRUCTURE | - |
dc.subject.keywordPlus | PHASE CAZRTI2O7 | - |
dc.subject.keywordPlus | SOLID-SOLUTION | - |
dc.subject.keywordPlus | WASTE FORMS | - |
dc.subject.keywordPlus | SELENITES | - |
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