DC Field | Value | Language |
---|---|---|
dc.contributor.author | Ullah, Zakir | ko |
dc.contributor.author | Sonawane, Prasad M. | ko |
dc.contributor.author | Nguyen, Thien S. | ko |
dc.contributor.author | Garai, Mousumi | ko |
dc.contributor.author | Churchill, David G. | ko |
dc.contributor.author | Yavuz, Cafer T. | ko |
dc.date.accessioned | 2021-06-30T00:50:08Z | - |
dc.date.available | 2021-06-30T00:50:08Z | - |
dc.date.created | 2021-06-30 | - |
dc.date.issued | 2021-10 | - |
dc.identifier.citation | SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, v.259 | - |
dc.identifier.issn | 1386-1425 | - |
dc.identifier.uri | http://hdl.handle.net/10203/286275 | - |
dc.description.abstract | A structurally characterized novel dual-pocketed tetra-conjugated bisphenol-based chromophore (fluorescence = 652 nm) was synthesized in gram scale in similar to 90% yield from its tetraaldehyde. Highly selective, naked-eye detection of CN- (DMSO/H2O) was confirmed by interferent testing. A detection limit of 0.38 mu M, within the permissible limit of CN- concentration in drinking water was achieved as mandated by WHO. The "reversibility" study shows potential applicability and reusability of Sen. Moreover, costeffective and on-site interfaces, application tools such as fabricated cotton swabs, plastic Petri dishes, and filter papers further demonstrated the specific selectivity of Sen for the toxic CN-. In addition, an easily available and handy smartphone-assisted "Color Picker" app was utilized to help estimate the concentration of CN- ion present. A dual phenol deprotonation mechanism is active and supported by H-1 NMR spectroscopic data and DFT calculation results. (C) 2021 Elsevier B.V. All rights reserved. | - |
dc.language | English | - |
dc.publisher | PERGAMON-ELSEVIER SCIENCE LTD | - |
dc.title | Bisphenol-based cyanide sensing: Selectivity, reversibility, facile synthesis, bilateral "OFF-ON" fluorescence, C-2 nu structural and conformational analysis | - |
dc.type | Article | - |
dc.identifier.wosid | 000663534100017 | - |
dc.identifier.scopusid | 2-s2.0-85105481636 | - |
dc.type.rims | ART | - |
dc.citation.volume | 259 | - |
dc.citation.publicationname | SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY | - |
dc.identifier.doi | 10.1016/j.saa.2021.119881 | - |
dc.contributor.localauthor | Churchill, David G. | - |
dc.contributor.localauthor | Yavuz, Cafer T. | - |
dc.contributor.nonIdAuthor | Sonawane, Prasad M. | - |
dc.contributor.nonIdAuthor | Nguyen, Thien S. | - |
dc.contributor.nonIdAuthor | Garai, Mousumi | - |
dc.description.isOpenAccess | N | - |
dc.type.journalArticle | Article | - |
dc.subject.keywordAuthor | Cyanide ion detection | - |
dc.subject.keywordAuthor | Bisphenol | - |
dc.subject.keywordAuthor | Chemosensing | - |
dc.subject.keywordAuthor | Reversible | - |
dc.subject.keywordAuthor | On-site economical application | - |
dc.subject.keywordAuthor | H-1 NMR | - |
dc.subject.keywordAuthor | UV-Vis spectroscopy | - |
dc.subject.keywordPlus | ANION | - |
dc.subject.keywordPlus | CHEMOSENSOR | - |
dc.subject.keywordPlus | UREA | - |
dc.subject.keywordPlus | DIAMINOMALEONITRILE | - |
dc.subject.keywordPlus | RECEPTORS | - |
dc.subject.keywordPlus | CHEMISTRY | - |
dc.subject.keywordPlus | THIOUREA | - |
dc.subject.keywordPlus | SENSORS | - |
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