Understanding the Origin of the Chiral Recognition of Esters with Octahedral Chiral Cobalt Complexes

Cited 1 time in webofscience Cited 0 time in scopus
  • Hit : 89
  • Download : 0
DC FieldValueLanguage
dc.contributor.authorJang, Suminko
dc.contributor.authorKim, Hyunwooko
dc.date.accessioned2021-04-26T06:10:23Z-
dc.date.available2021-04-26T06:10:23Z-
dc.date.created2021-03-22-
dc.date.issued2021-04-
dc.identifier.citationASIAN JOURNAL OF ORGANIC CHEMISTRY, v.10, no.4, pp.886 - 890-
dc.identifier.issn2193-5807-
dc.identifier.urihttp://hdl.handle.net/10203/282562-
dc.description.abstractHere, we report a combined experimental and computational study to understand the chiral recognition of cationic cobalt complexes with esters. The cationic cobalt complexes were synthesized by stereoselective assembly of ligands to the cobalt center. The tetradentate N2O2 ligand was used to control the metal-centered chirality, and the bidentate diamine ligand played an important role in the chiral discrimination of esters by H-1 NMR spectroscopy. The phenyl rings of the cobalt complexes additively enhanced the chiral discrimination. The opposite chiralities of the N2O2 ligand and bidentate diamine ligand constituted a well-matched combination, which was further demonstrated by computational analysis of 1 : 2 binding models of the cationic cobalt complex and 1-phenylethyl acetate.-
dc.languageEnglish-
dc.publisherWILEY-V C H VERLAG GMBH-
dc.titleUnderstanding the Origin of the Chiral Recognition of Esters with Octahedral Chiral Cobalt Complexes-
dc.typeArticle-
dc.identifier.wosid000624632400001-
dc.identifier.scopusid2-s2.0-85101901438-
dc.type.rimsART-
dc.citation.volume10-
dc.citation.issue4-
dc.citation.beginningpage886-
dc.citation.endingpage890-
dc.citation.publicationnameASIAN JOURNAL OF ORGANIC CHEMISTRY-
dc.identifier.doi10.1002/ajoc.202100022-
dc.contributor.localauthorKim, Hyunwoo-
dc.description.isOpenAccessN-
dc.type.journalArticleArticle-
dc.subject.keywordAuthorchiral analysis-
dc.subject.keywordAuthorchiral solvating agent-
dc.subject.keywordAuthorenantiomeric excess-
dc.subject.keywordAuthorNMR spectroscopy-
dc.subject.keywordAuthordensity functional calculation-
Appears in Collection
CH-Journal Papers(저널논문)
Files in This Item
There are no files associated with this item.
This item is cited by other documents in WoS
⊙ Detail Information in WoSⓡ Click to see webofscience_button
⊙ Cited 1 items in WoS Click to see citing articles in records_button

qr_code

  • mendeley

    citeulike


rss_1.0 rss_2.0 atom_1.0