DC Field | Value | Language |
---|---|---|
dc.contributor.author | Jung, Sungwoo | ko |
dc.contributor.author | Shin, Sanghoon | ko |
dc.contributor.author | Park, Seongjin | ko |
dc.contributor.author | Hong, Sungwoo | ko |
dc.date.accessioned | 2021-03-26T02:52:12Z | - |
dc.date.available | 2021-03-26T02:52:12Z | - |
dc.date.created | 2020-07-27 | - |
dc.date.issued | 2020-07 | - |
dc.identifier.citation | JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, v.142, no.26, pp.11370 - 11375 | - |
dc.identifier.issn | 0002-7863 | - |
dc.identifier.uri | http://hdl.handle.net/10203/281979 | - |
dc.description.abstract | Reported herein is a general strategy for the photochemical cross-coupling between N-amidopyridinium salts and various alkyl bromides under photocatalyst-free conditions, granting facile access to various C4-alkylated pyridines. This approach exploits the intriguing photochemical activity of electron donor-acceptor (EDA) complexes between N-amidopyridinium salts and bromide, which provides a photoactive handle capable of generating silyl radicals and driving the alkylation process. The robustness of this protocol was further demonstrated by the late-stage functionalization of complex compounds under mild and metal-free conditions. | - |
dc.language | English | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.title | Visible-Light-Driven C4-Selective Alkylation of Pyridinium Derivatives with Alkyl Bromides | - |
dc.type | Article | - |
dc.identifier.wosid | 000547329800007 | - |
dc.identifier.scopusid | 2-s2.0-85087465603 | - |
dc.type.rims | ART | - |
dc.citation.volume | 142 | - |
dc.citation.issue | 26 | - |
dc.citation.beginningpage | 11370 | - |
dc.citation.endingpage | 11375 | - |
dc.citation.publicationname | JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | - |
dc.identifier.doi | 10.1021/jacs.0c04499 | - |
dc.contributor.localauthor | Hong, Sungwoo | - |
dc.description.isOpenAccess | N | - |
dc.type.journalArticle | Article | - |
dc.subject.keywordPlus | BOND-DISSOCIATION ENERGIES | - |
dc.subject.keywordPlus | C-H ALKYLATION | - |
dc.subject.keywordPlus | METAL-FREE | - |
dc.subject.keywordPlus | N-OXIDES | - |
dc.subject.keywordPlus | ELECTRON-TRANSFER | - |
dc.subject.keywordPlus | PHOTOREDOX | - |
dc.subject.keywordPlus | HETEROARENES | - |
dc.subject.keywordPlus | FUNCTIONALIZATION | - |
dc.subject.keywordPlus | ALCOHOLS | - |
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