Clean Ar-Me conversion to Ar-aldehyde with the aid of carefully designed metallocorrole photocatalysts

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dc.contributor.authorZhan, Xuanko
dc.contributor.authorKolanu, Sudhakarko
dc.contributor.authorFite, Shacharko
dc.contributor.authorChen, Qiu-Chengko
dc.contributor.authorLee, Woohyunko
dc.contributor.authorChurchill, David G.ko
dc.contributor.authorGross, Zeevko
dc.date.accessioned2021-03-26T02:32:14Z-
dc.date.available2021-03-26T02:32:14Z-
dc.date.created2020-08-31-
dc.date.issued2020-08-
dc.identifier.citationPHOTOCHEMICAL & PHOTOBIOLOGICAL SCIENCES, v.19, no.8, pp.996 - 1000-
dc.identifier.issn1474-905X-
dc.identifier.urihttp://hdl.handle.net/10203/281937-
dc.description.abstractToluene,p-xylene and mesitylene were cleanly converted to their corresponding monoaldehydesviamild photooxygenation utilizing transition metal and main group beta-CF3-substituted corroles. Aldehyde yield increased as more electron-donating CH(3)groups are present on the substrate.4-Pwas most efficient (TON similar to 1072, mesitylene)viathe singlet oxygen vis the superoxide mechanism.-
dc.languageEnglish-
dc.publisherROYAL SOC CHEMISTRY-
dc.titleClean Ar-Me conversion to Ar-aldehyde with the aid of carefully designed metallocorrole photocatalysts-
dc.typeArticle-
dc.identifier.wosid000558538800001-
dc.identifier.scopusid2-s2.0-85089404842-
dc.type.rimsART-
dc.citation.volume19-
dc.citation.issue8-
dc.citation.beginningpage996-
dc.citation.endingpage1000-
dc.citation.publicationnamePHOTOCHEMICAL & PHOTOBIOLOGICAL SCIENCES-
dc.identifier.doi10.1039/d0pp00218f-
dc.contributor.localauthorChurchill, David G.-
dc.contributor.nonIdAuthorZhan, Xuan-
dc.contributor.nonIdAuthorKolanu, Sudhakar-
dc.contributor.nonIdAuthorFite, Shachar-
dc.contributor.nonIdAuthorChen, Qiu-Cheng-
dc.contributor.nonIdAuthorGross, Zeev-
dc.description.isOpenAccessN-
dc.type.journalArticleArticle-
dc.subject.keywordPlusOXIDATION-
dc.subject.keywordPlusTOLUENE-
dc.subject.keywordPlusTRIFLUOROMETHYLATION-
dc.subject.keywordPlusCATALYST-
dc.subject.keywordPlusOXYGEN-
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