Assembly of Thiosubstituted Benzoxazoles via Copper-Catalyzed Coupling of Thiols with 5-Iodotriazoles Serving as Diazo Surrogates

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dc.contributor.authorKotovshchikov Y.N.ko
dc.contributor.authorLatyshev G.V.ko
dc.contributor.authorKirillova E.A.ko
dc.contributor.authorMoskalenko, Uliana D,ko
dc.contributor.authorLukashev N.V.ko
dc.contributor.authorBeletskaya I.P.ko
dc.date.accessioned2021-03-05T00:50:04Z-
dc.date.available2021-03-05T00:50:04Z-
dc.date.created2021-03-05-
dc.date.created2021-03-05-
dc.date.issued2020-07-
dc.identifier.citationJournal of Organic Chemistry, v.85, no.14, pp.9015 - 9028-
dc.identifier.issn0022-3263-
dc.identifier.urihttp://hdl.handle.net/10203/281226-
dc.description.abstractAn efficient cascade approach to thiosubstituted benzoxazoles has been developed. The transformation starts with in situ generation of a diazo compound via annulation-triggered electrocyclic opening of the 1,2,3-triazole ring. The subsequent Cu-catalyzed trapping of diazo intermediates by various thiols affords the desired heterocycles in generally good yields of up to 91%. The protocol features very good functional group tolerance and is applicable to substrates with different electronic properties.-
dc.languageEnglish-
dc.publisherAmerican Chemical Society-
dc.titleAssembly of Thiosubstituted Benzoxazoles via Copper-Catalyzed Coupling of Thiols with 5-Iodotriazoles Serving as Diazo Surrogates-
dc.typeArticle-
dc.identifier.scopusid2-s2.0-85089275271-
dc.type.rimsART-
dc.citation.volume85-
dc.citation.issue14-
dc.citation.beginningpage9015-
dc.citation.endingpage9028-
dc.citation.publicationnameJournal of Organic Chemistry-
dc.identifier.doi10.1021/acs.joc.0c00931-
dc.contributor.localauthorMoskalenko, Uliana D,-
dc.contributor.nonIdAuthorKotovshchikov Y.N.-
dc.contributor.nonIdAuthorLatyshev G.V.-
dc.contributor.nonIdAuthorKirillova E.A.-
dc.contributor.nonIdAuthorLukashev N.V.-
dc.contributor.nonIdAuthorBeletskaya I.P.-
dc.description.isOpenAccessN-
dc.type.journalArticleArticle-
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