Solvent-Free Photobiocatalytic Hydroxylation of Cyclohexane

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dc.contributor.authorHobisch, Markusko
dc.contributor.authorvan Schie, Morten Martinus Cornelis Haraldko
dc.contributor.authorKim, Jinhyunko
dc.contributor.authorAndersen, Kasper Rojkjaerko
dc.contributor.authorAlcalde, Miguelko
dc.contributor.authorKourist, Robertko
dc.contributor.authorPark, Chan Beumko
dc.contributor.authorHollmann, Frankko
dc.contributor.authorKara, Selinko
dc.date.accessioned2020-11-04T06:55:06Z-
dc.date.available2020-11-04T06:55:06Z-
dc.date.created2020-06-29-
dc.date.issued2020-08-
dc.identifier.citationCHEMCATCHEM, v.12, no.16, pp.4009 - 4013-
dc.identifier.issn1867-3880-
dc.identifier.urihttp://hdl.handle.net/10203/277114-
dc.description.abstractThe use of neat reaction media, that is the avoidance of additional solvents, is the simplest and the most efficient approach to follow in biocatalysis. Here, we show that unspecific peroxygenase fromAgrocybe aegerita(AaeUPO) can hydroxylate the neat model substrate cyclohexane. H(2)O(2)was photocatalytically generated in situ by nitrogen-doped carbon nanodots (N-CNDs) and UV LED illumination.AaeUPO entrapment in alginate beads increased enzyme stability and facilitated the reaction in neat cyclohexane. N-CNDs absorption in beads containingAaeUPO created a 2-in-1 heterogeneous photobiocatalyst that was active for up to seven days under reaction conditions and produced cyclohexanol, 2.5 mM. To increase productivity, the bead size and the photocatalyst-to-enzyme ratio have been identified as promising targets for optimisation.-
dc.languageEnglish-
dc.publisherWILEY-V C H VERLAG GMBH-
dc.titleSolvent-Free Photobiocatalytic Hydroxylation of Cyclohexane-
dc.typeArticle-
dc.identifier.wosid000539635000001-
dc.identifier.scopusid2-s2.0-85086247340-
dc.type.rimsART-
dc.citation.volume12-
dc.citation.issue16-
dc.citation.beginningpage4009-
dc.citation.endingpage4013-
dc.citation.publicationnameCHEMCATCHEM-
dc.identifier.doi10.1002/cctc.202000512-
dc.contributor.localauthorPark, Chan Beum-
dc.contributor.nonIdAuthorHobisch, Markus-
dc.contributor.nonIdAuthorvan Schie, Morten Martinus Cornelis Harald-
dc.contributor.nonIdAuthorAndersen, Kasper Rojkjaer-
dc.contributor.nonIdAuthorAlcalde, Miguel-
dc.contributor.nonIdAuthorKourist, Robert-
dc.contributor.nonIdAuthorHollmann, Frank-
dc.contributor.nonIdAuthorKara, Selin-
dc.description.isOpenAccessY-
dc.type.journalArticleArticle-
dc.subject.keywordAuthorPhotobiocatalysis-
dc.subject.keywordAuthornon-conventional media-
dc.subject.keywordAuthorcarbon nanodots-
dc.subject.keywordAuthororganic media-
dc.subject.keywordAuthorhydroxylation-
dc.subject.keywordPlusCATALYZED OXYFUNCTIONALIZATION-
dc.subject.keywordPlusOXIDATION-
dc.subject.keywordPlusPEROXIDASE-
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