Quantifying the nitrogen effect on CO2 capture using isoporous network polymers

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The impact of nitrogen atoms on CO2 binding was evaluated for two isostructural porous bisimidazole-linked polymers (BILPs), which serendipitously had identical surface areas and pore size distributions, a very rare observation. The two structures differ only in the core of the trialdehyde component, the nitrogen atom (BILP-19) versus benzene ring (BILP-5). Such a slight difference, however, has brought about a stronger CO2 capture capacity of BILP-19 and hence increased CO2/N-2 separation capability.
Publisher
ROYAL SOC CHEMISTRY
Issue Date
2020-04
Language
English
Article Type
Article
Citation

CHEMICAL COMMUNICATIONS, v.56, no.31, pp.4273 - 4275

ISSN
1359-7345
DOI
10.1039/d0cc00982b
URI
http://hdl.handle.net/10203/274167
Appears in Collection
EEW-Journal Papers(저널논문)
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