Directed self-assembly of a helical nanofilament liquid crystal phase for use as structural color reflectors

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The fabrication of molecular structures with a desired morphology, e.g., nanotubes, nanoribbons, nanosprings, and sponges, is essential for the advancement of nanotechnology. Unfortunately, realization of this objective is expensive and complicated. Here, we report that irradiating a film comprising azobenzene derivatives with UV light produces oriented arrays of helical nanofilaments via the photoisomerization-induced Weigert effect. As a result, structural colors are observed due to the extrinsic chiral reflection in the visible wavelength range, and the reflected color can be tuned by adjusting the molecular length of the azobenzene derivative. This simple fabrication method can be used for fabricating large, reversible, and patternable color reflectors, providing a new platform for interference-based structural coloration as it exists in nature, such as morpho butterflies, green-winged teal, and various beetles.
Publisher
NATURE PUBLISHING GROUP
Issue Date
2019-08
Language
English
Article Type
Article
Citation

NPG ASIA MATERIALS, v.11

ISSN
1884-4049
DOI
10.1038/s41427-019-0146-6
URI
http://hdl.handle.net/10203/267443
Appears in Collection
NT-Journal Papers(저널논문)
Files in This Item
[2019] NPG. Asia_Directed self-assembly of a helical nanofilament liquid crystal phase for use as structural color reflectors.pdf(1.52 MB)Download
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