Borane-catalyzed hydrosilylation of unsaturated bonds including conjugated carbonyls and ynamides = 붕소 촉매를 이용한 불포화 카보닐과 아인아마이드의 수소화규소 반응에 대한 연구

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Hydrosilylation is one of the most straightforward chemical method to afford organisilicons which are extensively utilized in diverse chemical applications. Among various catalytic hydrosilylation method, nonmetallic tris(pentafluorophenyl)borane $B(C_6F_5)_3$-catalyzed hydrosilylation reaction is worthy of considerable notice, which bearing distinct mechanistic property and various substrate applicability. This thesis includes overall investigations of borane-catalyzed hydrosilylation of unsaturated bonds especially dealing with conjugated carbonyls and ynamides. Especially, on the basis of either experimental or computational studies, the concealed mechanistic features of present borane catalyzed organic transformations are properly uncovered.
Advisors
Chang, Sukbokresearcher장석복researcher
Description
한국과학기술원 :화학과,
Publisher
한국과학기술원
Issue Date
2018
Identifier
325007
Language
eng
Description

학위논문(박사) - 한국과학기술원 : 화학과, 2018.2,[iv, 41 p. :]

Keywords

hydrosilylation▼aunsaturated bonds▼aorganosilicons▼anonmetallic borane catalys; 수소화규소 반응▼a불포화 결합▼a유기규소화합물▼a비금속 붕소촉매

URI
http://hdl.handle.net/10203/265498
Link
http://library.kaist.ac.kr/search/detail/view.do?bibCtrlNo=734460&flag=dissertation
Appears in Collection
CH-Theses_Ph.D.(박사논문)
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