The existence of dual Cu site involved in the selective catalytic reduction of NO with propene on Cu/ZSM-5

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In order to establish the role of surface species in the selective catalytic reduction (SCR), in situ IR studies were carried out using a DRIFT (diffuse reflectance infrared Fourier transform) cell in gas mixtures of various C3H6/NO ratios containing excess oxygen. The location and mobility of Cu ions were investigated by recording the relevant bands of CO adsorbed on Cu/ZSM-5. The nitro species coordinated on Cu(2+)and the -NCO surface complex as possible intermediates were observed in the reduction of NO with propene on Cu/ZSM-5 between 350 and 400 degrees C. The reactivities of these species toward NO, O-2 and propene were examined. The nitro species can react with propene very rapidly to form N-2 without the formation of NCO species. NCO also reacts with NO2 and/or NO at 350 degrees C. IR spectra of CO adsorbed on cuprous ions show that two kinds of Cu ions, which are responsible for the activation of NO and propene respectively, exist on Cu/ZSM-5. From these results, a dual site mechanism involving nitro species and -NCO species as intermediates is suggested.
Publisher
BALTZER SCI PUBL BV
Issue Date
1996
Language
English
Article Type
Article
Keywords

NITRIC-OXIDE REDUCTION; EXCHANGED ZEOLITES; CU-ZSM-5 CATALYSTS; NITROGEN MONOXIDE; LEAN CONDITIONS; OXIDATION; OXYGEN; HYDROCARBONS; STATE; IONS

Citation

CATALYSIS LETTERS, v.42, no.3-4, pp.177 - 184

ISSN
1011-372X
URI
http://hdl.handle.net/10203/250724
Appears in Collection
CBE-Journal Papers(저널논문)
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