Polymerization of methyl methacrylate with Ni(II) alpha-diimine/MAO and Fe(II) and Co(II) pyridyl bis(imine)/MAO

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Polymerizations of methyl methacrylate with (alpha-diimine)nickel(II)/methylaluminoxane (MAO) and (pyridyl bis(imine))iron(II) and (pyridyl bis(imine))cobalt-(II)/MAO are reported. Effects of structural variation of the ligand on the activities of catalysts and polymer microstructure are described. The catalyst systems gave syndio-rich poly(methyl methacrylate). The alpha-diimine system showed much higher activity than the pyridyl bis(imine) systems under similar polymerization conditions.
Publisher
WILEY-V C H VERLAG GMBH
Issue Date
2003-05
Language
English
Article Type
Article
Keywords

POLY(METHYL METHACRYLATE); CATALYSTS; ETHYLENE; COPOLYMERIZATION; OLEFINS; METALLOCENES; COMPLEXES; POLYMERS; MONOMERS

Citation

MACROMOLECULAR RAPID COMMUNICATIONS, v.24, no.8, pp.508 - 511

ISSN
1022-1336
URI
http://hdl.handle.net/10203/250649
Appears in Collection
CBE-Journal Papers(저널논문)
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