Zigzag-Shaped Silver Nanoplates: Synthesis via Ostwald Ripening and Their Application in Highly Sensitive Strain Sensors

Abstract

Zigzag-shaped Ag nanoplates display unique anisotropic planar structures with unusual jagged edges and relatively large lateral dimensions. These characteristics make such nanoplates promising candidates for metal inks in printed electronics, which can be used for realizing stretchable electrodes. In the current work, we used a one-pot coordination-based synthetic strategy to synthesize zigzag-shaped Ag nanoplates. In the synthetic procedure, cyanuric acid was used both as a ligand of the Ag+ ion, hence producing complex structures and controlling the kinetics of the reduction of the cation, and as a capping agent that promoted the lateral growth of the Ag nanoplates. Hence, cyanuric acid played a crucial role in the formation of zigzag-shaped nanoplates. In contrast to previous studies that reported oriented attachment to be the predominant mechanism responsible for the growth of zigzag-shaped nanoplates, Ostwald ripening was the dominant growth mechanism in the current work. Our findings on the particle morphology and crystalline structure of the Ag nanoplates motivated us to use them as conductive materials for stretchable strain sensors. Strain sensors based on nanocomposites of our zigzag-shaped Ag nanoplate and polydimethylsiloxane in the form of a sandwich structure were successfully produced by following a simple, low-cost, and solution-processable method. The strain sensors exhibited extremely high sensitivity (gauge factor approximate to 2000), high stretchability with a linear response (approximate to 27%), and high reliability, all of which allowed the sensor to monitor diverse human motions, including joint movement and phonation.