DC Field | Value | Language |
---|---|---|
dc.contributor.author | Zhang, Jianbo | ko |
dc.contributor.author | Park, Sehoon | ko |
dc.contributor.author | Chang, Sukbok | ko |
dc.date.accessioned | 2018-11-22T06:41:54Z | - |
dc.date.available | 2018-11-22T06:41:54Z | - |
dc.date.created | 2018-11-13 | - |
dc.date.created | 2018-11-13 | - |
dc.date.issued | 2018-10 | - |
dc.identifier.citation | JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, v.140, no.41, pp.13209 - 13213 | - |
dc.identifier.issn | 0002-7863 | - |
dc.identifier.uri | http://hdl.handle.net/10203/246696 | - |
dc.description.abstract | Described herein is the development of an unprecedented route to bridged sila-N-heterocycles via B(C6F5)(3)-catalyzed cascade silylation of N-aryl piperidines with hydrosilanes. Mechanistic studies indicated that an outer-sphere ionic path is operative to involve three sequential catalytic steps having N-silyl piperidinium borohydride as a resting species: (i) dehydrogenation of the piperidine ring, (ii) beta-selective hydrosilylation of a resultant enamine intermediate, and (iii) intramolecular dehydrogenative sp(2) C-H silylation. | - |
dc.language | English | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.subject | H SILYLATION | - |
dc.subject | B(C6F5)(3)-CATALYZED HYDROSILYLATION | - |
dc.subject | AROMATIC HETEROCYCLES | - |
dc.subject | REDUCTION | - |
dc.subject | HYDROSILANES | - |
dc.subject | AMINES | - |
dc.subject | ACTIVATION | - |
dc.subject | INHIBITORS | - |
dc.subject | MECHANISM | - |
dc.subject | SILICON | - |
dc.title | Catalytic Access to Bridged Sila-N-heterocycles from Piperidines via Cascade sp(3) and sp(2) C-Si Bond Formation | - |
dc.type | Article | - |
dc.identifier.wosid | 000447953600016 | - |
dc.identifier.scopusid | 2-s2.0-85054680466 | - |
dc.type.rims | ART | - |
dc.citation.volume | 140 | - |
dc.citation.issue | 41 | - |
dc.citation.beginningpage | 13209 | - |
dc.citation.endingpage | 13213 | - |
dc.citation.publicationname | JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | - |
dc.identifier.doi | 10.1021/jacs.8b08733 | - |
dc.contributor.localauthor | Chang, Sukbok | - |
dc.contributor.nonIdAuthor | Zhang, Jianbo | - |
dc.contributor.nonIdAuthor | Park, Sehoon | - |
dc.description.isOpenAccess | N | - |
dc.type.journalArticle | Article | - |
dc.subject.keywordPlus | H SILYLATION | - |
dc.subject.keywordPlus | B(C6F5)(3)-CATALYZED HYDROSILYLATION | - |
dc.subject.keywordPlus | AROMATIC HETEROCYCLES | - |
dc.subject.keywordPlus | REDUCTION | - |
dc.subject.keywordPlus | HYDROSILANES | - |
dc.subject.keywordPlus | AMINES | - |
dc.subject.keywordPlus | ACTIVATION | - |
dc.subject.keywordPlus | INHIBITORS | - |
dc.subject.keywordPlus | MECHANISM | - |
dc.subject.keywordPlus | SILICON | - |
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