DC Field | Value | Language |
---|---|---|
dc.contributor.author | Ahn, Yun-Ho | ko |
dc.contributor.author | Shin, Kyuchul | ko |
dc.contributor.author | Lee, Jae Woo | ko |
dc.date.accessioned | 2018-08-21T04:39:35Z | - |
dc.date.available | 2018-08-21T04:39:35Z | - |
dc.date.created | 2018-08-20 | - |
dc.date.created | 2018-08-20 | - |
dc.date.created | 2018-08-20 | - |
dc.date.issued | 2018-08 | - |
dc.identifier.citation | CHEMICAL PHYSICS LETTERS, v.706, pp.14 - 18 | - |
dc.identifier.issn | 0009-2614 | - |
dc.identifier.uri | http://hdl.handle.net/10203/245175 | - |
dc.description.abstract | The lattice expansion and thermal behavior of gamma-irradiated unstable clathrate hydrates are explored to understand the complex physicochemical properties of clathrate hydrates. A previous study revealed that enclathrated methyl vinyl ketone molecules show a peculiar conformational change via a ketyl radical anion after c-irradiation with an annealing process. We measured the lattice parameters of gamma-irradiated binary methyl vinyl ketone + CH4, O-2, and N-2 hydrates at various temperatures. We observed that induced radical affects the lattice expansion behavior, and the thermal expansion coefficients of gamma-irradiated hydrates highly depend on the types of secondary gaseous guest molecules. (C) 2018 Elsevier B.V. All rights reserved. | - |
dc.language | English | - |
dc.publisher | ELSEVIER SCIENCE BV | - |
dc.title | Thermal expansivity of gamma-irradiated clathrate hydrate with intracavity conformational change | - |
dc.type | Article | - |
dc.identifier.wosid | 000440458100003 | - |
dc.identifier.scopusid | 2-s2.0-85047561750 | - |
dc.type.rims | ART | - |
dc.citation.volume | 706 | - |
dc.citation.beginningpage | 14 | - |
dc.citation.endingpage | 18 | - |
dc.citation.publicationname | CHEMICAL PHYSICS LETTERS | - |
dc.identifier.doi | 10.1016/j.cplett.2018.05.060 | - |
dc.contributor.localauthor | Lee, Jae Woo | - |
dc.contributor.nonIdAuthor | Shin, Kyuchul | - |
dc.description.isOpenAccess | N | - |
dc.type.journalArticle | Article | - |
dc.subject.keywordAuthor | Clathrate hydrate | - |
dc.subject.keywordAuthor | Thermal expansivity | - |
dc.subject.keywordAuthor | gamma-irradiation | - |
dc.subject.keywordAuthor | Intracavity conformational change | - |
dc.subject.keywordAuthor | Secondary guest effect | - |
dc.subject.keywordPlus | LATTICE EXPANSION | - |
dc.subject.keywordPlus | HYDROGEN-TRANSFER | - |
dc.subject.keywordPlus | GUEST MOLECULES | - |
dc.subject.keywordPlus | GAS | - |
dc.subject.keywordPlus | STABILITY | - |
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