Design of metal loaded zeolites as dual functional adsorbent/catalyst system for VOC control

Cited 0 time in webofscience Cited 0 time in scopus
  • Hit : 343
  • Download : 24
DC FieldValueLanguage
dc.contributor.authorBaek, Se-Won-
dc.contributor.authorKim, Jeong-Rang-
dc.contributor.authorIhm, Son-Ki-
dc.date.accessioned2011-06-20T02:05:20Z-
dc.date.available2011-06-20T02:05:20Z-
dc.date.issued2004-
dc.identifier.citationInternational Zeolite Conferenceen
dc.identifier.urihttp://hdl.handle.net/10203/24102-
dc.description.abstractMetal loaded zeolite HY was proposed as dual functional adsorbent/catalyst media for the control of low concentration VOC streams, which has both high adsorption capacity and catalytic activity. To design a good dual functional system, both adsorption and catalytic activity test were carried out. Hydrophobic HY zeolite showed a high adsorption capacity comparable to activated carbon and better desorption features for the cyclic operation. Metal addition endowed HY zeolite adsorbent with catalytic activity for VOC oxidation, which should be applicable to the dual functional adsorption/catalytic oxidation system. The temperature programmed surface reaction (TPSR) of toluene and methylethylketone suggested the silver as the best candidate among the tested transition metals. Temperature programmed reductions (TPR) and O2- temperature programmed desorption (O2-TPD) on Ag/HY catalysts were carried out to explain the nature of active centre of Ag catalyst for the toluene oxidation. Silver oxide species or partially oxidized metallic silver on to the surface of metallic silver phase was proposed as an active redox site during the oxidation reaction.en
dc.description.sponsorshipThis research was supported by the Ecotechnopia 21 project of KIEST, Korea Institute of Environmental Science and Technology. The financial support from National Research Laboratory (NRL) Project of Korea Ministry of Science and Technology and Brain Korea 21 program were also kindly provided for this work.en
dc.language.isoen_USen
dc.publisherElsevieren
dc.subjectVOCen
dc.subjectAg loaded zeolite HYen
dc.subjectadsorptionen
dc.subjectcatalytic oxidationen
dc.subjecthydrophobic molecular sieve (HMS)en
dc.subjectdual functional adsorbent/catalysten
dc.titleDesign of metal loaded zeolites as dual functional adsorbent/catalyst system for VOC controlen
dc.typeArticleen

qr_code

  • mendeley

    citeulike


rss_1.0 rss_2.0 atom_1.0