A fluorescent chemosensor for Al3+ based on julolidine and tryptophan moieties

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dc.contributor.authorChoi, Ye Wonko
dc.contributor.authorLee, Jae Junko
dc.contributor.authorNam, Eunjuko
dc.contributor.authorLim, Mi Heeko
dc.contributor.authorKim, Chealko
dc.date.accessioned2018-02-21T06:06:12Z-
dc.date.available2018-02-21T06:06:12Z-
dc.date.created2018-02-08-
dc.date.created2018-02-08-
dc.date.created2018-02-08-
dc.date.issued2016-04-
dc.identifier.citationTETRAHEDRON, v.72, no.16, pp.1998 - 2005-
dc.identifier.issn0040-4020-
dc.identifier.urihttp://hdl.handle.net/10203/240274-
dc.description.abstractA new and simple fluorescent chemosensor 1, based on julolidine and tryptophan moieties, has been synthesized and characterized. The sensor 1 displayed a selective and sensitive detecting ability for aluminum (III) ion by 'OFF ON' fluorescent response in aqueous solution. This sensing mechanism might be due to the inhibition of C=N isomerization, and the activation of chelation enhanced fluorescence (CHEF). This sensing mechanism of 1 for Al3+ was supported by theoretical calculations. Moreover, sensor I had a low detection limit (6.4 mu M), which is below than the WHO recommendation level (7.41 I'M) for drinking water. Importantly, the chemosensor 1 could be applied to living cells to detect Al3+. Therefore, the sensor 1 can be employed as a practical fluorescent chemosensor for recognition of Al3+ in aqueous solution. (C) 2016 Elsevier Ltd. All rights reserved.-
dc.languageEnglish-
dc.publisherPERGAMON-ELSEVIER SCIENCE LTD-
dc.titleA fluorescent chemosensor for Al3+ based on julolidine and tryptophan moieties-
dc.typeArticle-
dc.identifier.wosid000374198700014-
dc.identifier.scopusid2-s2.0-84960193949-
dc.type.rimsART-
dc.citation.volume72-
dc.citation.issue16-
dc.citation.beginningpage1998-
dc.citation.endingpage2005-
dc.citation.publicationnameTETRAHEDRON-
dc.identifier.doi10.1016/j.tet.2016.02.066-
dc.contributor.localauthorLim, Mi Hee-
dc.contributor.nonIdAuthorChoi, Ye Won-
dc.contributor.nonIdAuthorLee, Jae Jun-
dc.contributor.nonIdAuthorNam, Eunju-
dc.contributor.nonIdAuthorKim, Cheal-
dc.description.isOpenAccessN-
dc.type.journalArticleArticle-
dc.subject.keywordAuthorFluorescent chemosensor-
dc.subject.keywordAuthorAluminum ion-
dc.subject.keywordAuthorC=N isomerization-
dc.subject.keywordAuthorCHEF-
dc.subject.keywordAuthorCell imaging-
dc.subject.keywordAuthorTheoretical calculations-
dc.subject.keywordPlusAQUEOUS-MEDIA-
dc.subject.keywordPlusCOLORIMETRIC SENSOR-
dc.subject.keywordPlusSELECTIVE DETECTION-
dc.subject.keywordPlusLIVING CELLS-
dc.subject.keywordPlusSCHIFF-BASE-
dc.subject.keywordPlusALUMINUM TOXICITY-
dc.subject.keywordPlusION CHEMOSENSORS-
dc.subject.keywordPlusON NAPHTHOL-
dc.subject.keywordPlusPROBE-
dc.subject.keywordPlusCU2+-
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