Dehydrosulfurative arylation with concomitant oxidative dehydrogenation for rapid access to pyrimidine derivatives

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This report describes a cascade reaction method for the synthesis of 2-arylpyrimidine derivatives via dehydrosulfurative carbon-carbon cross-coupling and concomitant oxidative dehydrogenation under a Pd/Cu catalytic system. It provides rapid and general access to a diverse range of 2-arylpyrimidines in a single step from a wide range of 3,4-dihydropyrimidin-1H-2-thiones (DHPMs) and arylboronic acids. (C) 2017 Elsevier Ltd. All rights reserved.
Publisher
PERGAMON-ELSEVIER SCIENCE LTD
Issue Date
2017-11
Language
English
Article Type
Article
Citation

TETRAHEDRON, v.73, no.47, pp.6604 - 6613

ISSN
0040-4020
DOI
10.1016/j.tet.2017.10.010
URI
http://hdl.handle.net/10203/228597
Appears in Collection
CH-Journal Papers(저널논문)
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