DSpace at KOASAS
College of Natural Sciences(자연과학대학)Dept. of Chemistry(화학과)CH-Journal Papers(저널논문)

Selective C-O Bond Cleavage of Sugars with Hydrosilanes Catalyzed by Piers' Borane Generated In Situ

Cited 29 time in webofscience Cited 0 time in scopus
  • Hit : 475
  • Download : 0
Export
DC FieldValueLanguage
dc.contributor.authorZhang, Jianboko
dc.contributor.authorPark, Sehoonko
dc.contributor.authorChang, Sukbokko
dc.date.accessioned2017-11-21T04:06:57Z-
dc.date.available2017-11-21T04:06:57Z-
dc.date.created2017-11-20-
dc.date.created2017-11-20-
dc.date.issued2017-10-
dc.identifier.citationANGEWANDTE CHEMIE-INTERNATIONAL EDITION, v.56, no.44, pp.13757 - 13761-
dc.identifier.issn1433-7851-
dc.identifier.urihttp://hdl.handle.net/10203/227209-
dc.description.abstractDescribed herein is the selective reduction of sugars with hydrosilanes catalyzed by using Piers' borane [(C6F5)(2)BH] generated in situ. The hydrosilylative C-O bond cleavage of silyl-protected mono-and disaccharides in the presence of a (C6F5)(2)BH catalyst, generated in situ from (C6F5)(2)BOH, takes place with excellent chemo- and regioselectivities to provide a range of polyols. A study of the substituent effects of sugars on the catalytic activity and selectivity revealed that the steric environment around the anomeric carbon (C1) is crucial.-
dc.languageEnglish-
dc.publisherWILEY-V C H VERLAG GMBH-
dc.subjectBIS(PENTAFLUOROPHENYL)BORINIC ACID-
dc.subjectB(C6F5)(3)-CATALYZED HYDROSILATION-
dc.subjectHYDROSILYLATION CATALYSTS-
dc.subjectALKENE HYDROSILYLATION-
dc.subjectTERTIARY SILANES-
dc.subjectALKYL ETHERS-
dc.subjectH-H-
dc.subjectREDUCTION-
dc.subjectHYDROGENATION-
dc.subjectDEOXYGENATION-
dc.titleSelective C-O Bond Cleavage of Sugars with Hydrosilanes Catalyzed by Piers' Borane Generated In Situ-
dc.typeArticle-
dc.identifier.wosid000413314800038-
dc.identifier.scopusid2-s2.0-85030479396-
dc.type.rimsART-
dc.citation.volume56-
dc.citation.issue44-
dc.citation.beginningpage13757-
dc.citation.endingpage13761-
dc.citation.publicationnameANGEWANDTE CHEMIE-INTERNATIONAL EDITION-
dc.identifier.doi10.1002/anie.201708109-
dc.contributor.localauthorChang, Sukbok-
dc.contributor.nonIdAuthorZhang, Jianbo-
dc.contributor.nonIdAuthorPark, Sehoon-
dc.description.isOpenAccessN-
dc.type.journalArticleArticle-
dc.subject.keywordAuthorbond cleavage-
dc.subject.keywordAuthorchemoselectivity-
dc.subject.keywordAuthorhydrosilylative reduction-
dc.subject.keywordAuthorPiers&apos-
dc.subject.keywordAuthorborane-
dc.subject.keywordAuthorsugars-
dc.subject.keywordPlusBIS(PENTAFLUOROPHENYL)BORINIC ACID-
dc.subject.keywordPlusB(C6F5)(3)-CATALYZED HYDROSILATION-
dc.subject.keywordPlusHYDROSILYLATION CATALYSTS-
dc.subject.keywordPlusALKENE HYDROSILYLATION-
dc.subject.keywordPlusTERTIARY SILANES-
dc.subject.keywordPlusALKYL ETHERS-
dc.subject.keywordPlusH-H-
dc.subject.keywordPlusREDUCTION-
dc.subject.keywordPlusHYDROGENATION-
dc.subject.keywordPlusDEOXYGENATION-
Appears in Collection
CH-Journal Papers(저널논문)
Files in This Item
There are no files associated with this item.
This item is cited by other documents in WoS
⊙ Detail Information in WoSⓡ Click to see webofscience_button
⊙ Cited 29 items in WoS Click to see citing articles in records_button

Display Simple Item Record

qr_code

  • mendeley

    citeulike

Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.


rss_1.0 rss_2.0 atom_1.0