Water as a Hydroxy Source in a Rh-III-Catalyzed Directed C-H Hydroxylation of 2-Arylpyridines

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dc.contributor.authorKim, Kiseongko
dc.contributor.authorHyun, Jaeyongko
dc.contributor.authorKim, Jinko
dc.contributor.authorKim, Hyunwooko
dc.date.accessioned2017-08-08T06:47:05Z-
dc.date.available2017-08-08T06:47:05Z-
dc.date.created2017-08-07-
dc.date.created2017-08-07-
dc.date.issued2017-07-
dc.identifier.citationASIAN JOURNAL OF ORGANIC CHEMISTRY, v.6, no.7, pp.907 - 912-
dc.identifier.issn2193-5807-
dc.identifier.urihttp://hdl.handle.net/10203/225214-
dc.description.abstractA [(RhCp)-Cp-III*]-catalyzed directed C-H hydroxylation of 2-arylpyridines is described (Cp*=1,2,3,4,5-pentamethylcyclopenta-2,4-dienyl), in which the combination of [(RhCp*Cl-2)(2)]/AgF, PhI(OPiv)(2), and water is used an effective catalytic system. According to our mechanistic studies, including O-18-labeling experiments and X-ray crystallographic analysis of an intermediate Rh complex, we demonstrate that water and PhI(OPiv)(2) are required for Rh catalysis as the hydroxy source and the oxidant, respectively.-
dc.languageEnglish-
dc.publisherWILEY-V C H VERLAG GMBH-
dc.subjectBOND ACTIVATION-
dc.subjectARENES-
dc.subjectFUNCTIONALIZATIONS-
dc.subjectOXYGENATION-
dc.subjectOXIDANT-
dc.subjectLIGAND-
dc.subjectOLEDS-
dc.subjectO-2-
dc.subjectIR-
dc.titleWater as a Hydroxy Source in a Rh-III-Catalyzed Directed C-H Hydroxylation of 2-Arylpyridines-
dc.typeArticle-
dc.identifier.wosid000405725900019-
dc.identifier.scopusid2-s2.0-85024384017-
dc.type.rimsART-
dc.citation.volume6-
dc.citation.issue7-
dc.citation.beginningpage907-
dc.citation.endingpage912-
dc.citation.publicationnameASIAN JOURNAL OF ORGANIC CHEMISTRY-
dc.identifier.doi10.1002/ajoc.201700196-
dc.contributor.localauthorKim, Hyunwoo-
dc.contributor.nonIdAuthorHyun, Jaeyong-
dc.description.isOpenAccessN-
dc.type.journalArticleArticle-
dc.subject.keywordAuthorC-H activation-
dc.subject.keywordAuthorhydroxylation-
dc.subject.keywordAuthorhypervalent compounds-
dc.subject.keywordAuthorrhodium-
dc.subject.keywordAuthorwater-
dc.subject.keywordPlusBOND ACTIVATION-
dc.subject.keywordPlusARENES-
dc.subject.keywordPlusFUNCTIONALIZATIONS-
dc.subject.keywordPlusOXYGENATION-
dc.subject.keywordPlusOXIDANT-
dc.subject.keywordPlusLIGAND-
dc.subject.keywordPlusOLEDS-
dc.subject.keywordPlusO-2-
dc.subject.keywordPlusIR-
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