Transparent Metal-Organic Framework/Polymer Mixed Matrix Membranes as Water Vapor Barriers

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Preventing the permeation of reactive molecules into electronic devices or photovoltaic modules is of great importance to ensure their life span and reliability. This work is focused on the formation of highly functioning barrier films based on nanocrystals (NCs) of a water-scavenging metal organic framework (MOP) and a hydrophobic cyclic olefin copolymer (COC) to overcome the current limitations. Water vapor transmission rates (WVTR) of the films reveal a 10-fold enhancement in the WVTR compared to the substrate while maintaining outstanding transparency over most of the visible and solar spectrum, a necessary condition for integration with optoelectronic devices.
Publisher
AMER CHEMICAL SOC
Issue Date
2016-04
Language
English
Article Type
Article
Citation

ACS APPLIED MATERIALS & INTERFACES, v.8, no.16, pp.10098 - 10103

ISSN
1944-8244
DOI
10.1021/acsami.6b01299
URI
http://hdl.handle.net/10203/221004
Appears in Collection
CBE-Journal Papers(저널논문)
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