Rh-III-Catalyzed Directed C-H Bromination and Iodination to Synthesize Atropisomeric Biaryls

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dc.contributor.authorKim, Kiseongko
dc.contributor.authorHyun, Jaeyongko
dc.contributor.authorKim, Jinko
dc.contributor.authorKim, Hyunwooko
dc.date.accessioned2016-11-30T08:44:38Z-
dc.date.available2016-11-30T08:44:38Z-
dc.date.created2016-11-16-
dc.date.created2016-11-16-
dc.date.issued2016-09-
dc.identifier.citationASIAN JOURNAL OF ORGANIC CHEMISTRY, v.5, no.9, pp.1107 - 1110-
dc.identifier.issn2193-5807-
dc.identifier.urihttp://hdl.handle.net/10203/214295-
dc.description.abstractThe [(RhCp)-Cp-III*]-catalyzed directed C-H bromination and iodination reactions of 2-aryl isoquinolines/pyridines are highly efficient and afford atropisomeric biaryl compounds (Cp*=1,2,3,4,5-pentamethylcyclopenta-2,4-dienyl) in good yields. Among several reported C-H bond halogenation methods, the combination of [(RhCp)-Cp-III*Cl-2](2)/AgSbF6, N-halosuccinimide, and pivalic acid in 1,2-dichloroethane is found to be the only effective catalytic system to provide atropisomeric 2-halogenated 2-aryl isoquinolines/pyridines-
dc.languageEnglish-
dc.publisherWILEY-V C H VERLAG GMBH-
dc.subjectDYNAMIC KINETIC RESOLUTION-
dc.subjectAXIALLY CHIRAL BIARYLS-
dc.subjectASYMMETRIC CATALYSIS-
dc.subjectENANTIOSELECTIVE SYNTHESIS-
dc.subjectNATURAL-PRODUCTS-
dc.subjectOPTICAL RESOLUTION-
dc.subjectBINAM DERIVATIVES-
dc.subjectLIGANDS-
dc.subject2-NAPHTHOLS-
dc.subjectEFFICIENT-
dc.titleRh-III-Catalyzed Directed C-H Bromination and Iodination to Synthesize Atropisomeric Biaryls-
dc.typeArticle-
dc.identifier.wosid000383686500003-
dc.identifier.scopusid2-s2.0-84978062454-
dc.type.rimsART-
dc.citation.volume5-
dc.citation.issue9-
dc.citation.beginningpage1107-
dc.citation.endingpage1110-
dc.citation.publicationnameASIAN JOURNAL OF ORGANIC CHEMISTRY-
dc.identifier.doi10.1002/ajoc.201600259-
dc.contributor.localauthorKim, Hyunwoo-
dc.contributor.nonIdAuthorHyun, Jaeyong-
dc.type.journalArticleArticle-
dc.subject.keywordAuthoratropisomerism-
dc.subject.keywordAuthorbiaryls-
dc.subject.keywordAuthorC-H activation-
dc.subject.keywordAuthorhalogenation-
dc.subject.keywordAuthorrhodium-
dc.subject.keywordPlusDYNAMIC KINETIC RESOLUTION-
dc.subject.keywordPlusAXIALLY CHIRAL BIARYLS-
dc.subject.keywordPlusASYMMETRIC CATALYSIS-
dc.subject.keywordPlusENANTIOSELECTIVE SYNTHESIS-
dc.subject.keywordPlusNATURAL-PRODUCTS-
dc.subject.keywordPlusOPTICAL RESOLUTION-
dc.subject.keywordPlusBINAM DERIVATIVES-
dc.subject.keywordPlusLIGANDS-
dc.subject.keywordPlus2-NAPHTHOLS-
dc.subject.keywordPlusEFFICIENT-
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