The formation of right-handed and left-handed chiral nanopores within a single domain during amino acid self-assembly on Au(111)

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We report the formation of both right- and left-handed chiral nanopores within a single domain during the self-assembly of an amino acid derivative on an inert Au(111) surface using STM. DFT calculations employed to rationalize this unusual result identified that intermolecular interactions between chiral, windmill-shaped tetramers are crucial for self-assembly.
Publisher
ROYAL SOC CHEMISTRY
Issue Date
2016-06
Language
English
Article Type
Article
Keywords

HYDROGEN-BONDS; SUPRAMOLECULAR CLUSTERS; ORGANIC-MOLECULES; SURFACES; DENSITY; GROWTH; NANOSTRUCTURES; COMBINATORIAL; RECOGNITION; ADSORPTION

Citation

PHYSICAL CHEMISTRY CHEMICAL PHYSICS, v.18, no.21, pp.14172 - 14176

ISSN
1463-9076
DOI
10.1039/C6CP01914E
URI
http://hdl.handle.net/10203/212146
Appears in Collection
CH-Journal Papers(저널논문)
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