DC Field | Value | Language |
---|---|---|
dc.contributor.author | Xie, Weilong | ko |
dc.contributor.author | Chang, Sukbok | ko |
dc.date.accessioned | 2016-06-28T02:04:22Z | - |
dc.date.available | 2016-06-28T02:04:22Z | - |
dc.date.created | 2016-03-08 | - |
dc.date.created | 2016-03-08 | - |
dc.date.issued | 2016-01 | - |
dc.identifier.citation | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, v.55, no.5, pp.1876 - 1880 | - |
dc.identifier.issn | 1433-7851 | - |
dc.identifier.uri | http://hdl.handle.net/10203/208007 | - |
dc.description.abstract | New reactivity of a [Cu(NHC)] (NHC = N-heterocyclic carbene) catalyst is disclosed for the efficient C-H allylation of polyfluoroarenes using allyl halides in benzene at room temperature. The same catalyst system also promotes an isomerization-induced alkenylation of initially the generated allyl arenes when the reaction is run in tetrahydrofuran. Significantly, not only electron-deficient but also electron-rich (hetero)arenes undergo this double-bond migration process, thus leading to alkenylated products. The present system features mild reaction conditions, broad scope with respect to the arene substrates and allyl halide reactants, good functional-group tolerance, and high stereoselectivity. | - |
dc.language | English | - |
dc.publisher | WILEY-V C H VERLAG GMBH | - |
dc.subject | BOND FUNCTIONALIZATION | - |
dc.subject | CATALYZED ISOMERIZATION | - |
dc.subject | AROMATIC-COMPOUNDS | - |
dc.subject | ARYLBORONIC ACIDS | - |
dc.subject | ARYL BROMIDES | - |
dc.subject | COPPER | - |
dc.subject | ALKENES | - |
dc.subject | ARYLATION | - |
dc.subject | OLEFINS | - |
dc.subject | MILD | - |
dc.title | [Cu(NHC)]-Catalyzed C-H Allylation and Alkenylation of both Electron-Deficient and Electron-Rich (Hetero)arenes with Allyl Halides | - |
dc.type | Article | - |
dc.identifier.wosid | 000369854000053 | - |
dc.identifier.scopusid | 2-s2.0-84955658308 | - |
dc.type.rims | ART | - |
dc.citation.volume | 55 | - |
dc.citation.issue | 5 | - |
dc.citation.beginningpage | 1876 | - |
dc.citation.endingpage | 1880 | - |
dc.citation.publicationname | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | - |
dc.identifier.doi | 10.1002/anie.201510180 | - |
dc.contributor.localauthor | Chang, Sukbok | - |
dc.contributor.nonIdAuthor | Xie, Weilong | - |
dc.type.journalArticle | Article | - |
dc.subject.keywordAuthor | alkenes | - |
dc.subject.keywordAuthor | allylic compounds | - |
dc.subject.keywordAuthor | copper | - |
dc.subject.keywordAuthor | isomerization | - |
dc.subject.keywordAuthor | N-heterocyclic carbenes | - |
dc.subject.keywordPlus | BOND FUNCTIONALIZATION | - |
dc.subject.keywordPlus | CATALYZED ISOMERIZATION | - |
dc.subject.keywordPlus | AROMATIC-COMPOUNDS | - |
dc.subject.keywordPlus | ARYLBORONIC ACIDS | - |
dc.subject.keywordPlus | ARYL BROMIDES | - |
dc.subject.keywordPlus | COPPER | - |
dc.subject.keywordPlus | ALKENES | - |
dc.subject.keywordPlus | ARYLATION | - |
dc.subject.keywordPlus | OLEFINS | - |
dc.subject.keywordPlus | MILD | - |
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