DC Field | Value | Language |
---|---|---|
dc.contributor.author | Oezdemir, E. | ko |
dc.contributor.author | Thirion, D. | ko |
dc.contributor.author | Yavuz, Cafer T | ko |
dc.date.accessioned | 2016-04-20T07:03:49Z | - |
dc.date.available | 2016-04-20T07:03:49Z | - |
dc.date.created | 2015-09-07 | - |
dc.date.created | 2015-09-07 | - |
dc.date.created | 2015-09-07 | - |
dc.date.issued | 2015 | - |
dc.identifier.citation | RSC ADVANCES, v.5, no.84, pp.69010 - 69015 | - |
dc.identifier.issn | 2046-2069 | - |
dc.identifier.uri | http://hdl.handle.net/10203/205667 | - |
dc.description.abstract | A new carbon-carbon bonded nanoporous polymer network was synthesized via efficient and catalyst free Knoevenagel-like condensation polymerization in near quantitative yields. The obtained polymer network, Covalent Organic Polymer - COP-100 possesses strong fluorescent properties and designed solubility in polar aprotic solvents, which shows promise for use as a metal-sensing material in solution. COP-100 exhibited high selectivity towards Fe2+ and Fe3+ in the presence of other common metal cations (Al3+, Ag+, Cd2+, Co2+, Cr3+, cu(2+), Hg2+, mg2+, mn(2+), Nat, Ni2+, zn(2+)) as the fluorescence of the polymer was significantly quenched even at very low concentrations. In the range from 2.5 x 10(-6) to 2 x 10(-4) M, a linear fluorescence emission response with equipment limited detection minimum of 2.13 x 10(-7) M and 2.45 x 10(-7) M for Fe2+ and Fe3+, respectively, was observed. These results suggest that COP-100 is a promising material as a selective fluorescence sensor for iron ions. | - |
dc.language | English | - |
dc.publisher | ROYAL SOC CHEMISTRY | - |
dc.title | Covalent organic polymer framework with C-C bonds as a fluorescent probe for selective iron detection | - |
dc.type | Article | - |
dc.identifier.wosid | 000359568400096 | - |
dc.identifier.scopusid | 2-s2.0-84939529321 | - |
dc.type.rims | ART | - |
dc.citation.volume | 5 | - |
dc.citation.issue | 84 | - |
dc.citation.beginningpage | 69010 | - |
dc.citation.endingpage | 69015 | - |
dc.citation.publicationname | RSC ADVANCES | - |
dc.identifier.doi | 10.1039/c5ra10697d | - |
dc.contributor.localauthor | Yavuz, Cafer T | - |
dc.contributor.nonIdAuthor | Oezdemir, E. | - |
dc.contributor.nonIdAuthor | Thirion, D. | - |
dc.description.isOpenAccess | N | - |
dc.type.journalArticle | Article | - |
dc.subject.keywordPlus | CONJUGATED MICROPOROUS POLYMERS | - |
dc.subject.keywordPlus | RECENT PROGRESS | - |
dc.subject.keywordPlus | CHEMOSENSORS | - |
dc.subject.keywordPlus | SEPARATION | - |
dc.subject.keywordPlus | DESIGN | - |
dc.subject.keywordPlus | CONDENSATION | - |
dc.subject.keywordPlus | DERIVATIVES | - |
dc.subject.keywordPlus | NETWORKS | - |
dc.subject.keywordPlus | SENSORS | - |
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