DC Field | Value | Language |
---|---|---|
dc.contributor.author | Chin, Jik | ko |
dc.contributor.author | Kwon, Soon Ho | ko |
dc.contributor.author | Kim, Hyunwoo | ko |
dc.contributor.author | Chin, Peter | ko |
dc.contributor.author | So, Soon Mog | ko |
dc.contributor.author | Kim, B. Moon | ko |
dc.date.accessioned | 2014-09-01T07:20:14Z | - |
dc.date.available | 2014-09-01T07:20:14Z | - |
dc.date.created | 2014-06-23 | - |
dc.date.created | 2014-06-23 | - |
dc.date.created | 2014-06-23 | - |
dc.date.issued | 2014-02 | - |
dc.identifier.citation | EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, no.4, pp.725 - 730 | - |
dc.identifier.issn | 1434-193X | - |
dc.identifier.uri | http://hdl.handle.net/10203/189229 | - |
dc.description.abstract | gamma,delta-Diamino acid structural motifs are commonly found in bioactive molecules. We report a one-pot reaction for the synthesis of gamma,delta-diimino esters with two adjacent chiral centers in enantiomerically pure form through diaza-Cope rearrangement reaction of diimines formed from (R,R)-1,2-bis(2-hydroxyphenyl)-1,2-diaminoethane (hpen) and alde-hydes. DFT computation provides interesting insights into the stereospecific rearrangement reaction. The crystal structure of a product diimine formed from the reaction of (R,R)-hpen and 2,6-dichlorobenzaldehyde shows that the reaction gives the product diimine in S,S configuration. | - |
dc.language | English | - |
dc.publisher | WILEY-V C H VERLAG GMBH | - |
dc.title | Stereospecific Synthesis of gamma,delta-Diamino Esters | - |
dc.type | Article | - |
dc.identifier.wosid | 000336261500005 | - |
dc.identifier.scopusid | 2-s2.0-84896719980 | - |
dc.type.rims | ART | - |
dc.citation.issue | 4 | - |
dc.citation.beginningpage | 725 | - |
dc.citation.endingpage | 730 | - |
dc.citation.publicationname | EUROPEAN JOURNAL OF ORGANIC CHEMISTRY | - |
dc.identifier.doi | 10.1002/ejoc.201301167 | - |
dc.embargo.liftdate | 9999-12-31 | - |
dc.embargo.terms | 9999-12-31 | - |
dc.contributor.localauthor | Kim, Hyunwoo | - |
dc.contributor.nonIdAuthor | Chin, Jik | - |
dc.contributor.nonIdAuthor | Kwon, Soon Ho | - |
dc.contributor.nonIdAuthor | Chin, Peter | - |
dc.contributor.nonIdAuthor | So, Soon Mog | - |
dc.contributor.nonIdAuthor | Kim, B. Moon | - |
dc.description.isOpenAccess | N | - |
dc.type.journalArticle | Article | - |
dc.subject.keywordAuthor | Synthetic methods | - |
dc.subject.keywordAuthor | Stereospecificity | - |
dc.subject.keywordAuthor | Diaza-Cope rearrangement | - |
dc.subject.keywordAuthor | Density functional calculations | - |
dc.subject.keywordPlus | DIAZA-COPE REARRANGEMENT | - |
dc.subject.keywordPlus | OSELTAMIVIR PHOSPHATE TAMIFLU | - |
dc.subject.keywordPlus | INFLUENZA NEURAMINIDASE INHIBITORS | - |
dc.subject.keywordPlus | EFFICIENT ASYMMETRIC-SYNTHESIS | - |
dc.subject.keywordPlus | H5N1 AVIAN INFLUENZA | - |
dc.subject.keywordPlus | (-)-OSELTAMIVIR PHOSPHATE | - |
dc.subject.keywordPlus | (-)-SHIKIMIC ACID | - |
dc.subject.keywordPlus | MOTHER DIAMINE | - |
dc.subject.keywordPlus | D-MANNOSE | - |
dc.subject.keywordPlus | FACTOR XA | - |
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