DC Field | Value | Language |
---|---|---|
dc.contributor.author | Go, Min Jeong | ko |
dc.contributor.author | Lee, Ji Min | ko |
dc.contributor.author | Lee, Kang Mun | ko |
dc.contributor.author | Oh, Chang Hwa | ko |
dc.contributor.author | Park, Ka Hyun | ko |
dc.contributor.author | Kim, So Han | ko |
dc.contributor.author | Kim, Min | ko |
dc.contributor.author | Park, Hyoung-Ryun | ko |
dc.contributor.author | Park, Myung Hwan | ko |
dc.contributor.author | Kim, Youngjo | ko |
dc.contributor.author | Lee, Junseong | ko |
dc.date.accessioned | 2014-08-29T01:29:37Z | - |
dc.date.available | 2014-08-29T01:29:37Z | - |
dc.date.created | 2014-02-17 | - |
dc.date.created | 2014-02-17 | - |
dc.date.issued | 2014-01 | - |
dc.identifier.citation | POLYHEDRON, v.67, pp.286 - 294 | - |
dc.identifier.issn | 0277-5387 | - |
dc.identifier.uri | http://hdl.handle.net/10203/188764 | - |
dc.description.abstract | The selective syntheses of titanium complexes containing the 2-(2H-benzo[d][1,2,3]triazol-2-yl)-4,6-ditert-pentylphenol (LH) ligand, namely [LTiCl2(mu-Cl)](2) (1), LTiCl3(THF) (2), L2Ti(NMe2)2 (3), L2TiCl2 (4) and L2Ti(O-i-Pr)2 (5), were achieved by changing the solvents or metal precursors. The solid state structures of 1-5 were revealed by single-crystal X-ray analyses. Complexes 2 and 5 showed a fast thermal exchange process of the benzotriazole ligand L. Among 1-5, complex 5 was proven as a highly effective catalyst for the controlled ring opening polymerization (ROP) of lactide (LA), as shown by the linearity of the molecular weight versus [LafTij ratio as well as very narrow PDI values of the PLA polymers obtained. | - |
dc.language | English | - |
dc.publisher | PERGAMON-ELSEVIER SCIENCE LTD | - |
dc.subject | CHELATING DIARYLOXO LIGANDS | - |
dc.subject | GROUP-4 METAL-COMPLEXES | - |
dc.subject | RAC-LACTIDE | - |
dc.subject | CYCLIC ESTERS | - |
dc.subject | EPSILON-CAPROLACTONE | - |
dc.subject | EFFICIENT CATALYSTS | - |
dc.subject | ZINC-COMPLEXES | - |
dc.subject | STRUCTURAL-CHARACTERIZATION | - |
dc.subject | ZIRCONIUM COMPLEXES | - |
dc.subject | ALUMINUM COMPLEXES | - |
dc.title | Titanium complexes containing bidentate benzotriazole ligands as catalysts for the ring opening polymerization of lactide | - |
dc.type | Article | - |
dc.identifier.wosid | 000329557200034 | - |
dc.identifier.scopusid | 2-s2.0-84885343287 | - |
dc.type.rims | ART | - |
dc.citation.volume | 67 | - |
dc.citation.beginningpage | 286 | - |
dc.citation.endingpage | 294 | - |
dc.citation.publicationname | POLYHEDRON | - |
dc.identifier.doi | 10.1016/j.poly.2013.09.017 | - |
dc.embargo.liftdate | 9999-12-31 | - |
dc.embargo.terms | 9999-12-31 | - |
dc.contributor.localauthor | Lee, Kang Mun | - |
dc.contributor.nonIdAuthor | Go, Min Jeong | - |
dc.contributor.nonIdAuthor | Lee, Ji Min | - |
dc.contributor.nonIdAuthor | Oh, Chang Hwa | - |
dc.contributor.nonIdAuthor | Park, Ka Hyun | - |
dc.contributor.nonIdAuthor | Kim, So Han | - |
dc.contributor.nonIdAuthor | Kim, Min | - |
dc.contributor.nonIdAuthor | Park, Hyoung-Ryun | - |
dc.contributor.nonIdAuthor | Park, Myung Hwan | - |
dc.contributor.nonIdAuthor | Kim, Youngjo | - |
dc.contributor.nonIdAuthor | Lee, Junseong | - |
dc.type.journalArticle | Article | - |
dc.subject.keywordAuthor | Titanium | - |
dc.subject.keywordAuthor | Bidentate ligand | - |
dc.subject.keywordAuthor | X-ray structure | - |
dc.subject.keywordAuthor | Ring opening polymerization | - |
dc.subject.keywordAuthor | Polylactide | - |
dc.subject.keywordPlus | CHELATING DIARYLOXO LIGANDS | - |
dc.subject.keywordPlus | GROUP-4 METAL-COMPLEXES | - |
dc.subject.keywordPlus | RAC-LACTIDE | - |
dc.subject.keywordPlus | CYCLIC ESTERS | - |
dc.subject.keywordPlus | EPSILON-CAPROLACTONE | - |
dc.subject.keywordPlus | EFFICIENT CATALYSTS | - |
dc.subject.keywordPlus | ZINC-COMPLEXES | - |
dc.subject.keywordPlus | STRUCTURAL-CHARACTERIZATION | - |
dc.subject.keywordPlus | ZIRCONIUM COMPLEXES | - |
dc.subject.keywordPlus | ALUMINUM COMPLEXES | - |
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